Catalytic synthesis of 2,5-bis-methoxymethylfuran: A promising cetane number improver for diesel

被引：100
作者：
Cao, Quan [1 ,2 ]
Liang, Wenyuan [1 ,2 ]
Guan, Jing [1 ]
Wang, Lei [3 ]
Qu, Qian [4 ]
Zhang, Xinzhi [1 ,5 ]
Wang, Xicheng [1 ]
Mu, Xindong [1 ]
机构：
[1] Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Shandong, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266061, Shandong, Peoples R China
[4] Natl Oceanog Ctr, Qingdao 266071, Shandong, Peoples R China
[5] RiSun Coal Chem Engn Ltd Co, Beijing 100070, Peoples R China
来源：
APPLIED CATALYSIS A-GENERAL | 2014年 / 481卷
关键词：
5-Hydroxymethylfurfural; 2,5-Bis-hydroxymethylfuran; 2,5-Bis-methoxymethylfuran; Catalysis; FURAN-DERIVATIVES; FURFURYL ALCOHOL; SOLID ACID; LIQUID; CONVERSION; BIOMASS; ETHERIFICATION; DEHYDRATION; SUGARS; COMPONENTS;
D O I：
10.1016/j.apcata.2014.05.003
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Efficient hydrogenation of 5-hydroxymethylfurfural (HMF) into 2,5-bis-hydroxymethylfuran(BHMF)was performed using a Cu/SiO2 catalyst, obtaining as high as 97% BHMF yield. In the presence of acidic ZSM-5 zeolite (HZSM-5), the synthesized BHMF further reacted with methanol, leading to 70% yield of corresponding 2,5-bis-methoxymethylfuran (BMMF). The target product BMMF was an excellent cetane number improver for diesel, proved by its cetane number of 80 (much higher than that of the commercial diesel), high flash point (90 degrees C) and low cold filter plugging point (<-37 degrees C). (C) 2014 Elsevier B.V. All rights reserved.
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收藏
页码：49 / 53
页数：5
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