Catalytic synthesis of 2,5-bis-methoxymethylfuran: A promising cetane number improver for diesel

被引：97

作者：

Cao, Quan ^{[1
,2
]}

Liang, Wenyuan ^{[1
,2
]}

Guan, Jing ^{[1
]}

Wang, Lei ^{[3
]}

Qu, Qian ^{[4
]}

Zhang, Xinzhi ^{[1
,5
]}

Wang, Xicheng ^{[1
]}

Mu, Xindong ^{[1
]}

机构：

[1] Chinese Acad Sci, CAS Key Lab Biobased Mat, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Shandong, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266061, Shandong, Peoples R China

[4] Natl Oceanog Ctr, Qingdao 266071, Shandong, Peoples R China

[5] RiSun Coal Chem Engn Ltd Co, Beijing 100070, Peoples R China

来源：

APPLIED CATALYSIS A-GENERAL | 2014年 / 481卷

关键词：

5-Hydroxymethylfurfural; 2,5-Bis-hydroxymethylfuran; 2,5-Bis-methoxymethylfuran; Catalysis; FURAN-DERIVATIVES; FURFURYL ALCOHOL; SOLID ACID; LIQUID; CONVERSION; BIOMASS; ETHERIFICATION; DEHYDRATION; SUGARS; COMPONENTS;

D O I：

10.1016/j.apcata.2014.05.003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Efficient hydrogenation of 5-hydroxymethylfurfural (HMF) into 2,5-bis-hydroxymethylfuran(BHMF)was performed using a Cu/SiO2 catalyst, obtaining as high as 97% BHMF yield. In the presence of acidic ZSM-5 zeolite (HZSM-5), the synthesized BHMF further reacted with methanol, leading to 70% yield of corresponding 2,5-bis-methoxymethylfuran (BMMF). The target product BMMF was an excellent cetane number improver for diesel, proved by its cetane number of 80 (much higher than that of the commercial diesel), high flash point (90 degrees C) and low cold filter plugging point (<-37 degrees C). (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：49 / 53

页数：5

共 42 条

[1] The selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using heterogeneous catalysts
Alamillo, Ricardo
Tucker, Mark
Chia, Mei
Pagan-Torres, Yomaira
Dumesic, James
[J]. GREEN CHEMISTRY, 2012, 14 (05) : 1413 - 1419
[2] Etherification and reductive etherification of 5-(hydroxymethyl)furfural: 5-(alkoxymethyl)furfurals and 2,5-bis(alkoxymethyl)furans as potential bio-diesel candidates
Balakrishnan, Madhesan
Sacia, Eric R.
Bell, Alexis T.
[J]. GREEN CHEMISTRY, 2012, 14 (06) : 1626 - 1634
[3] From 5-Hydroxymethylfurfural (HMF) to Polymer Precursors: Catalyst Screening Studies on the Conversion of 1,2,6-hexanetriol to 1,6-hexanediol
Buntara, Teddy
Noel, Sebastien
Phua, Pim Huat
Melian-Cabrera, Ignacio
de Vries, Johannes G.
Heeres, Hero J.
[J]. TOPICS IN CATALYSIS, 2012, 55 (7-10) : 612 - 619
[4] Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone
Buntara, Teddy
Noel, Sebastien
Phua, Pim Huat
Melian-Cabrera, Ignacio
de Vries, Johannes G.
Heeres, Hero J.
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (31) : 7083 - 7087
[5] Catalytic selective etherification of hydroxyl groups in 5-hydroxymethylfurfural over H4SiW12O40/MCM-41 nanospheres for liquid fuel production
Che, Penghua
Lu, Fang
Zhang, Junjie
Huang, Yizheng
Nie, Xin
Gao, Jin
Xu, Jie
[J]. BIORESOURCE TECHNOLOGY, 2012, 119 : 433 - 436
[6] A two-step approach for the catalytic conversion of glucose to 2,5-dimethylfuran in ionic liquids
Chidambaram, Mandan
Bell, Alexis T.
[J]. GREEN CHEMISTRY, 2010, 12 (07) : 1253 - 1262
[7] Add-Functionalized SBA-15-Type Silica Catalysts for Carbohydrate Dehydration
Crisci, Anthony J.
Tucker, Mark H.
Lee, Ming-Yung
Jang, Se Gyu
Dumesic, James A.
Scott, Susannah L.
[J]. ACS CATALYSIS, 2011, 1 (07): : 719 - 728
[8] Dautzenberg F., 2009, [No title captured], Patent No. [WO 2009/030512, 2009030512]
[9] Promising results with YXY Diesel components in an ESC test cycle using a PACCAR Diesel engine
de Jong, Ed
Vijlbrief, Thomas
Hijkoop, Rene
Gruter, Gert-Jan M.
van der Waal, Jan C.
[J]. BIOMASS & BIOENERGY, 2012, 36 : 151 - 159
[10] One-Pot Conversions of Lignocellulosic and Algal Biomass into Liquid Fuels
De, Sudipta
Dutta, Saikat
Saha, Basudeb
[J]. CHEMSUSCHEM, 2012, 5 (09) : 1826 - 1833

← 1 2 3 4 5 →