Diamond, the best thermal conductor known, is the ultimate choice as a substrate material for the fabrication of denser, smaller and faster electronic packages. Consequently, in recent years, worldwide efforts have focused on the design of manufacturing transparent technologies for post-synthesis processing (polishing, planarization, metallization, die attach, etc.) of diamond substrates. In this study, a manufacturing-transparent, cost-effective, non-vacuum, laser-assisted coarse polishing technique for thick free-standing CVD diamond substrates was investigated [2]. The thickness of the substrates varied from 700 to 1000 mu m, with the average grain size ranging from 150 to 200 mu m. The average surface roughness (R-a) of the substrates, measured using contact surface profilometry, was between 20 and 30 mu m. The substrates were initially irradiated with a Nd-YAG laser (lambda = 532 nm) for coarse material removal, followed by an ArF excimer laser (lambda = 193 nm) for finer surface finishing. Under optimized conditions, the average surface roughness (R-a) was reduced from 25 to 5 mu m with the Nd-YAG laser, and further to less than or equal to 1 mu m with the excimer laser. The technique, which is the fastest processing technique known to the authors, is capable of polishing a 1 cm x 1 cm x 0.07 cm substrate in 50 s. (C) 1997 Elsevier Science S.A.