Concise Total Synthesis of (+)-Disparlure and its trans-Isomer Using Asymmetric Organocatalysis

被引：23

作者：

Kim, Sung-Gon ^{[1
]}

机构：

[1] Kyonggi Univ, Coll Nat Sci, Dept Chem, Suwon 443760, South Korea

来源：

SYNTHESIS-STUTTGART | 2009年 / 14期

关键词：

disparture; total synthesis; organocatalysis; asymmetric synthesis; olefin cross metathesis; EFFICIENT TOTAL-SYNTHESIS; GYPSY-MOTH; ALPHA; PHEROMONES; CONVERSION; ALDEHYDES;

D O I：

10.1055/s-0029-1216855

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The efficient enantioselective synthesis of(+)-disparlure and its trans-isomer is described. This approach involves tandem asymmetric organocatalytic alpha-aminoxylation-allytation of an aldehyde and olefin cross metathesis using Grubbs' catalyst as key steps.

引用

页码：2418 / 2422

页数：5

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