Electron transport in electrospun TiO2 nanofiber dye-sensitized solar cells

被引:102
作者
Mukherjee, Kunal [1 ]
Teng, Tai-Hou [1 ]
Jose, Rajan [1 ]
Ramakrishna, Seeram [1 ]
机构
[1] Natl Univ Singapore, Nanosci & Nanotechnol Initiat, Singapore 117576, Singapore
关键词
EFFICIENCY;
D O I
10.1063/1.3167298
中图分类号
O59 [应用物理学];
学科分类号
摘要
In this study dye-sensitized solar cells (DSCs) were fabricated using electrospun TiO2 nanofibers. Electrochemical impedance spectroscopy and open-circuit voltage decay were used to analyze electron transport in electrospun nanofibers and determine their applicability in DSCs. The polycrystalline nature and random web structure of the nanofibers exhibit effective electron diffusion coefficients close to that of high efficiency nanoparticle cells. The electron lifetime was, however, low due to the presence of a large number of surface traps despite the presence of a space-charge recombination barrier. (C) 2009 American Institute of Physics. [DOI: 10.1063/1.3167298]
引用
收藏
页数:3
相关论文
共 14 条
[1]   Determination of rate constants for charge transfer and the distribution of semiconductor and electrolyte electronic energy levels in dye-sensitized solar cells by open-circuit photovoltage decay method [J].
Bisquert, J ;
Zaban, A ;
Greenshtein, M ;
Mora-Seró, I .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (41) :13550-13559
[2]   Doubling exponent models for the analysis of porous film electrodes by impedance.: Relaxation of TiO2 nanoporous in aqueous solution [J].
Bisquert, J ;
Garcia-Belmonte, G ;
Fabregat-Santiago, F ;
Ferriols, NS ;
Bogdanoff, P ;
Pereira, EC .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (10) :2287-2298
[3]   Dye-sensitized solar cells with conversion efficiency of 11.1% [J].
Chiba, Yasuo ;
Islam, Ashraful ;
Watanabe, Yuki ;
Komiya, Ryoichi ;
Koide, Naoki ;
Han, Liyuan .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (24-28) :L638-L640
[4]   Electron transport and recombination in polycrystalline TiO2 nanowire dye-sensitized solar cells [J].
Enache-Pommer, Emil ;
Boercker, Janice E. ;
Aydil, Eray S. .
APPLIED PHYSICS LETTERS, 2007, 91 (12)
[5]   Correlation between photovoltaic performance and impedance spectroscopy of dye-sensitized solar cells based on ionic liquids [J].
Fabregat-Santiago, Francisco ;
Bisquert, Juan ;
Palomares, Emilio ;
Otero, Luis ;
Kuang, Daibin ;
Zakeeruddin, Shaik M. ;
Gratzel, Michael .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (17) :6550-6560
[6]   Spray deposition of electrospun TiO2 nanorods for dye-sensitized solar cell [J].
Fujihara, K. ;
Kumar, A. ;
Jose, R. ;
Ramakrishna, S. ;
Uchida, S. .
NANOTECHNOLOGY, 2007, 18 (36)
[7]   Axon guidance - Follow the leader [J].
Green, E .
NATURE REVIEWS NEUROSCIENCE, 2003, 4 (11) :859-859
[8]   Dye-sensitized solar cells using network structure of electrospun ZnO nanofiber mats [J].
Kim, Il-Doo ;
Hong, Jae-Min ;
Lee, Byong Hong ;
Kim, Dong Young ;
Jeon, Eun-Kyung ;
Choi, Duck-Kyun ;
Yang, Dae-Jin .
APPLIED PHYSICS LETTERS, 2007, 91 (16)
[9]   Electrospinning: A simple and versatile technique for producing ceramic nanofibers and nanotubes [J].
Li, Dan ;
McCann, Jesse T. ;
Xia, Younan .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (06) :1861-1869
[10]   Dynamics of charge transport and recombination in ZnO nanorod array dye-sensitized solar cells [J].
Martinson, Alex B. F. ;
McGarrah, James E. ;
Parpia, Mohammed O. K. ;
Hupp, Joseph T. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (40) :4655-4659