The metal chemistry of the carbahemiporphyrazines

被引：23

作者：

Durfee, William S. ^{[1
]}

Ziegler, Christopher J. ^{[2
]}

机构：

[1] SUNY Coll Buffalo, Dept Chem, Buffalo, NY 14222 USA

[2] Univ Akron, Dept Chem, Akron, OH 44325 USA

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2009年 / 13卷 / 03期

关键词：

phthalocyanine; porphyrazine; hemiporphyrazine; macrocycle; metal complexes; N-CONFUSED PORPHYRIN; CARBON-SUBSTITUTED HEMIPORPHYRAZINE; ORGANOMETALLIC CHEMISTRY; COMPLEXES; ACTIVATION; OXIDATION;

D O I：

10.1142/S1088424609000413

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Over fifty years ago, Linstead and Elvidge described the syntheses of phthalocyanine-like macrocycles in which one or two of the interior metal-binding nitrogen atoms were replaced with aromatic C-H groups. We review here the coordination chemistry of two of these systems, dicarbahemiporphyrazine and benziphthalocyanine, and we emphasize the unusual reactivity displayed by these macrocycles and the varying extent to which the C-H groups are activated by metal-binding.

引用

页码：304 / 311

页数：8

共 26 条

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