Bottom-up approach synthesis of core-shell nanoscale zerovalent iron (CS-nZVI): Physicochemical and spectroscopic characterization with Cu(II) ions adsorption application

Single pot system in chemical reduction via bottom-up approach was used for the synthesis of core shell nanoscale zerovalent iron (CS-nZVI). CS-nZVI was characterized by a combination of physicochemical and spectroscopic techniques. Data obtained showed BET surface area 20.8643 m(2)/g, t-Plot micropore volume 0.001895 cm(3)/g, BJH volume pores 0.115083 cm(3)/g, average pore width 186.9268 A, average pore diameter 240.753 A, PZC 5.24, and pH 6.80. Surface plasmon Resonance from UV-Vis spectrophotometer was observed at 340 nm. Surface morphology from SEM and TEM revealed a spherical cluster and chain-like nanostructure of size range 15.425 nm -97.566 nm. Energy Dispersive XRF revealed an elemental abundance of 96.05% core shell indicating the dominance of nZVI. EDX showed an intense peak of nZVI at 6.2 keV. FTIR data revealed the surface functional groups of Fe-O with characteristics peaks at 686.68 cm(-1), 569.02 cm(-1) and 434 cm(-1). In a batch technique, effective adsorption of endocrine disruptive Cu(II) ions was operational parameters dependent. Isotherm and kinetics studies were validated by statistical models. The study revealed unique characteristics of CS-nZVI and its efficacy in waste water treatment. (C) 2020 The Authors. Published by Elsevier B.V.