Ionic liquid analogues formed from hydrated metal salts

被引：326

作者：

Abbott, AP ^{[1
]}

Capper, G ^{[1
]}

Davies, DL ^{[1
]}

Rasheed, RK ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2004年 / 10卷 / 15期

关键词：

chromium; electrochemistry; green chemistry; ionic liquids;

D O I：

10.1002/chem.200400127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A dark green, viscous liquid can be formed by mixing choline chloride with chromium(iii) chloride hexahydrate and the physical properties are characteristic of an ionic liquid. The eutectic composition is found to be 1:2 choline chloride/chromium chloride. The viscosity and conductivity are measured as a function of temperature and composition and explained in terms of the ion size and liquid void volume. The electrochemical response of the ionic liquid is also characterised and it is shown that chromium can be electrodeposited efficiently to yield a crack-free deposit. This approach could circumvent the use of chromic acid for chromium electroplating, which would be a major environmental benefit. This method of using hydrated metal salts to form ionic liquids is shown to be valid for a variety of other salt mixtures with choline chloride.

引用

页码：3769 / 3774

页数：6

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