Synthesis of a Fluorescent Solvatochromic Resin Using Suzuki-Miyaura Cross-Coupling and Its Optical Waveguide Spectra to Measure the Solvent Polarity on the Surface

被引：2
作者：
Otsuka, Yu [1 ]
Li, Guanglei [2 ]
Takahashi, Hiromi [3 ]
Satoh, Hisashi [4 ]
Yamada, Koji [1 ,5 ]
机构：
[1] Hokkaido Univ, Grad Sch Environm Sci, Div Mat Sci, Sapporo, Hokkaido 0600810, Japan
[2] Nanjing Univ Finance & Econ, Sch Food Sci & Technol, Nanjing 210023, Peoples R China
[3] ATR Scientists Partners Inc, 3-27-13 Maehara, Koganei, Tokyo 1840013, Japan
[4] Hokkaido Univ, Div Environm Engn, Fac Engn, Sapporo, Hokkaido 0608628, Japan
[5] Hokkaido Univ, Fac Environm Earth Sci, Div Mat Sci, Sapporo, Hokkaido 0600810, Japan
来源：
MATERIALS | 2020年 / 13卷 / 20期
关键词：
Suzuki– Miyaura cross-coupling; solid-phase synthesis; optical waveguide spectrometry; PHASE PEPTIDE-SYNTHESIS; SENSOR; ACID; DYES;
D O I：
10.3390/ma13204483
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We have established a novel analytical method for solvent polarity on resin surface by combining the synthesis of fluorescent solvatochromic resin with optical waveguide spectrometry. The fluorescent solvatochromic resin was obtained via Suzuki-Miyaura cross-coupling between 4-iodobenzoic acid immobilized on Wang resin and 5-[4-(N,N-dihexylamino)phenyl]-2-thienylboronic acid N-methyl-iminodiacetic acid (MIDA) ester. The optical waveguide spectrometry studies on the resin showed a strong fluorescent solvatochromism in various organic solvents.
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页码：1 / 10
页数：10
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