An empirical equation for polymer electrolyte fuel cell (PEFC) behaviour

被引：164

作者：

Squadrito, G ^{[1
]}

Maggio, G ^{[1
]}

Passalacqua, E ^{[1
]}

Lufrano, F ^{[1
]}

Patti, A ^{[1
]}

机构：

[1] CNR, ITAE, I-98126 Messina, Italy

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1999年 / 29卷 / 12期

关键词：

electrochemical cells; mass transport; modelling; polymer electrolyte fuel cell;

D O I：

10.1023/A:1003890219394

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A simple analytical expression to determine cell potential (E) against current density (i) behaviour in polymer electrolyte fuel cells (PEFCs) was derived. The equation describes experimental data over the whole range of current density taking into account possible mass transport limitations. The empirical equation was used to fit experimental data obtained in a 50 cm(2) single cell in H-2/air operation using electrodes with low Pt loading (similar to 0.1 mg cm(-2)). A good agreement between theoretical and experimental data was found.

引用

页码：1449 / 1455

页数：7

共 24 条

[1]

AMPHLETT JC, 1995, J ELECTROCHEM SOC, V142, P1, DOI 10.1149/1.2043866

[2]

ATKINS PW, 1986, PHYSICAL CHEM

[3] A MATHEMATICAL-MODEL OF THE SOLID-POLYMER-ELECTROLYTE FUEL-CELL [J].