Molecular structure design and soft template synthesis of aza-, oxaaza- and thiaazamacrocyclic metal chelates in the gelatin matrix

被引：15

作者：

Mikhailov, Oleg V. ^{[1
]}

机构：

[1] Kazan Natl Res Technol Univ, Dept Analyt Chem, K Marx St 68, Kazan 420015, Russia

来源：

ARABIAN JOURNAL OF CHEMISTRY | 2017年 / 10卷 / 01期

关键词：

Soft template synthesis; Molecular structure design; Metal chelate; QUANTUM-CHEMICAL CALCULATION; MACROCYCLIC SCHIFF-BASE; 3D M(II) IONS; CU(II)-CONTAINING HETEROCYCLIC-COMPOUNDS; TERNARY-SYSTEM; COORDINATION-COMPOUNDS; GEOMETRIC PARAMETERS; IMMOBILIZED MATRIX; TETRAAZAMACROCYCLIC COMPLEXES; SPECTRAL CHARACTERIZATION;

D O I：

10.1016/j.arabjc.2016.10.014

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The data about of soft template synthesis proceeding in gelatin matrices in [3d-element M(II) ion - (N, S)-or (N, O, S)-ambidentate ligson - mono- or dicarbonyl ligson] systems, have been considered and discussed. The chemical nature of the final products of template synthesis formed under these specific conditions, has been compared with the chemical nature of the final products formed by template synthesis in solutions. It has been noted that in many cases, the nature and chemical composition of these products differ substantially. Specific features of the DFT calculated molecular structures of the macrocyclic compounds that can be formed due to the template synthesis in the systems indicated above, have been discussed, too. The review covers the period 1990-2015. (C) 2016 The Author. Production and hosting by Elsevier B.V. on behalf of King Saud University.

引用

页码：47 / 67

页数：21

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