Investigation of Sensing Characteristic of Flexible Arrayed RuO2 Chlorine Ion Sensor Modified by Graphene Oxide

被引:1
|
作者
Tseng, Shi-Chang [1 ]
Wu, Tong-Yu [1 ]
Chou, Jung-Chuan [2 ]
Liao, Yi-Hung [3 ]
Lai, Chih-Hsien [2 ]
Yan, Siao-Jie [2 ]
Tseng, Ting-Wei [4 ]
机构
[1] Natl Yunlin Univ Sci & Technol, Grad Sch Mech Engn, Touliu 64002, Taiwan
[2] Natl Yunlin Univ Sci & Technol, Grad Sch Elect Engn, Touliu 64002, Taiwan
[3] TransWorld Univ, Dept Informat & Elect Commerce Management, Touliu, Yunlin 64063, Taiwan
[4] Natl Yunlin Univ Sci & Technol, Dept Elect Engn, Touliu 64002, Yunlin, Taiwan
关键词
Ruthenium dioxide; graphene oxide; response time; interference effect; hysteresis effect and drift effect; CARBON;
D O I
10.1109/TSM.2018.2802486
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, the response time, interfering effect, drift effect, and hysteresis effect were investigated for the flexible arrayed ruthenium dioxide (RuO2)/0.01 wt% graphene oxide (GO) chlorine ion sensor. The best response time was 2 s in 10(-2) M and 1 M NaCl solutions. The KNO3, CaSO4, CaCO3, K2SO4, NaHCO3, and NaI solutions were dropped in 10(-5) M NaCl solution for interference measurement. The experimental results proved that the flexible arrayed RuO2/0.01 wt% GO chlorine ion sensor has good selectivity. The hysteresis potentials of the flexible arrayed RuO2/0.01 wt% GO chlorine ion sensor were 1.548 mV and 1.138 mV in the NaCl solutions during the cycles of 1 M -> 10(-1) M -> 1 M -> 10(-3) M -> 1 M and 1 M -> 10(-3) M -> 1 M -> 10(-1) M -> 1 M, respectively. The drift rate of the flexible arrayed RuO2/0.01 wt% GO chlorine ion sensor was 0.186 mV/hr in 10(-2) M NaCl solution. According the experiment result, the GO was used to modify the RuO2 sensing membrane, and the 0.01 wt% GO increased the sensing film conductivity and could reduce the response time, hysteresis effect and drift effect.
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页码:295 / 301
页数:7
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