Nature and properties of metal cations in aqueous solutions

被引:0
|
作者
Grzybkowski, W. [1 ]
机构
[1] Gdansk Tech Univ, Dept Phys Chem, PL-80952 Gdansk, Poland
来源
POLISH JOURNAL OF ENVIRONMENTAL STUDIES | 2006年 / 15卷 / 04期
关键词
solutions; ionization; cations; solutions structure; hydration; water exchange; hydrolysis; acidity; sea water;
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Chemical nature, thermodynamic and kinetic properties of metal cations in aqueous solutions are described and discussed in terms of structural factors controlling physical properties of the systems. The structure of hydrated cations, reaction mechanism of water exchange on the cations, hydrolytic phenomena and acidity of the cations are presented. Correlations between coordination states of the salts in and bulk properties of the solutions are indicated. Elements of aquatic chemistry are presented.
引用
收藏
页码:655 / 663
页数:9
相关论文
共 50 条
  • [1] Radiation of Aqueous Solutions of Salts with Multiply Charged Cations and Their Dielectric Properties in the Millimeter Band
    Lyashchenko, A. K.
    Efimov, A. Yu.
    Dunyashev, V. S.
    Karataeva, I. M.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 65 (02) : 241 - 246
  • [2] Quantitative evaluation of key properties of dry and wet metal oxides and metal hydroxides as well as of their potential determining cations in aqueous solutions
    Rosenholm, Jarl B.
    ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2022, 301
  • [3] Calculating the thermodynamic properties of aqueous solutions of alkali metal carboxylates
    Rudakov, A. M.
    Sergievskii, V. V.
    Zhukova, T. V.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (06) : 903 - 907
  • [4] Calculating the thermodynamic properties of aqueous solutions of alkali metal carboxylates
    A. M. Rudakov
    V. V. Sergievskii
    T. V. Zhukova
    Russian Journal of Physical Chemistry A, 2014, 88 : 903 - 907
  • [5] Radiation of Aqueous Solutions of Salts with Multiply Charged Cations and Their Dielectric Properties in the Millimeter Band
    A. K. Lyashchenko
    A. Yu. Efimov
    V. S. Dunyashev
    I. M. Karataeva
    Russian Journal of Inorganic Chemistry, 2020, 65 : 241 - 246
  • [6] Coordination polyhedra of hydration shells of Na+ and K+ cations in aqueous solutions
    Teplukhin, AV
    RUSSIAN CHEMICAL BULLETIN, 1999, 48 (05) : 842 - 848
  • [7] Preparation of zeolite A by inorganic complex precursor route for efficient elimination of heavy metal cations from aqueous solutions
    Hashemi, Seyed Mohsen
    Salehirad, Alireza
    Nasri, Zarrin
    INORGANIC AND NANO-METAL CHEMISTRY, 2023, 53 (01) : 66 - 77
  • [8] Coordination polyhedra of hydration shells of Na+ and K+ cations in aqueous solutions
    A. V. Teplukhin
    Russian Chemical Bulletin, 1999, 48 : 842 - 848
  • [9] Two-Dimensional Infrared Spectroscopy of Aqueous Solutions of Metal Nitrates: Slowdown of Spectral Diffusion in the Presence of Divalent Cations
    Das, Banshi
    Mondal, Subhadip
    Chandra, Amalendu
    JOURNAL OF PHYSICAL CHEMISTRY B, 2020, 124 (34) : 7391 - 7404
  • [10] On the elastic nature of the demixing transition of aqueous PNIPAM solutions
    Philipp, Martine
    Mueller, Ulrich
    Aleksandrova, Ralitsa
    Sanctuary, Roland
    Mueller-Buschbaum, Peter
    Krueger, Jan K.
    SOFT MATTER, 2012, 8 (44) : 11387 - 11395