Synthesis of an architectural electrode based on manganese oxide and carbon nanotubes for flexible supercapacitors

被引:14
|
作者
Zhang, Jinhui [1 ,2 ]
Zang, Jianbing [1 ]
Huang, Junjie [1 ]
Wang, Yanhui [1 ]
Xin, Guoxiang [1 ]
机构
[1] Yanshan Univ, Coll Mat Sci & Engn, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China
[2] Tangshan Coll, Tangshan 063000, Hebei, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon nanotubes; Nanocomposites; Electrodeposition; Supercapacitors; COMPOSITES; ARRAYS; MICROSTRUCTURE; PERFORMANCE; DEPOSITION; NANOWIRES;
D O I
10.1016/j.matlet.2014.04.039
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report the synthesis of an architectural electrode by electrophoretic deposition of carbon nanotubes (CNTs) on a graphite sheet (GS) substrate, followed by electrodeposition of manganese oxide (MnO2) nanoclusters into a three-dimensional network structure of CNT to form MnO2 embedded-CNTs/GS. The novel architecture, in which disconnected MnO2 nanoclusters were embedded in an interconnected 3D CNT network, was beneficial to improve the electrochemical utilization of MnO2 for charge storage. Therefore, the MnO2 embedded-CNTs/GS showed a fairly high specific capacitance of 540.7 F/g (based on MnO2), an excellent rate capability and a good cycling stability (less 10% loss of its initial capacitance after 1000 cycles). (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:24 / 27
页数:4
相关论文
共 50 条
  • [41] Carbon Xerogel and Manganese Oxide Capacitive Materials for Advanced Supercapacitors
    Lufrano, F.
    Staiti, P.
    Calvo, E. G.
    Juarez-Perez, E. J.
    Menendez, J. A.
    Arenillas, A.
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2011, 6 (03): : 596 - 612
  • [42] Layer-opened graphene paper with carbon nanotubes as support in a flexible electrode material for supercapacitors
    Ma, Zhihua
    Yang, Jie
    Zhang, Jingwei
    Chen, Gairong
    Miao, Changqing
    Shi, Lu
    Wang, Liujie
    Zhang, Zhijun
    JOURNAL OF ALLOYS AND COMPOUNDS, 2019, 775 : 982 - 989
  • [43] Flexible symmetric and asymmetric supercapacitors based in nanocomposites of carbon cloth/polyaniline - carbon nanotubes
    Bavio, M. A.
    Acosta, G. G.
    Kessler, T.
    Visintin, A.
    ENERGY, 2017, 130 : 22 - 28
  • [44] Synthesis and characterization of hybrid composites based on carbon nanotubes
    Canobre, Sheila C.
    Almeida, Dalva A. L.
    Fonseca, Carla Polo
    Neves, Silmara
    ELECTROCHIMICA ACTA, 2009, 54 (26) : 6383 - 6388
  • [45] Encapsulation of manganese oxides nanocrystals in electrospun carbon nanofibers as free-standing electrode for supercapacitors
    Zhao, Xin
    Du, Yuxuan
    Li, Yingzhi
    Zhang, Qinghua
    CERAMICS INTERNATIONAL, 2015, 41 (06) : 7402 - 7410
  • [46] Composite films prepared by immersion deposition of manganese oxide in carbon nanotubes grown on graphite for supercapacitors
    Li, Lingchuan
    Lafdi, Khalid
    JOURNAL OF MATERIALS SCIENCE, 2011, 46 (22) : 7328 - 7334
  • [47] Synthesis of manganese (IV) oxide at activated carbon on reduced graphene oxide sheets via laser irradiation technique for organic binder-free electrodes in flexible supercapacitors
    Qahtan, Talal F.
    Cevik, Emre
    Gondal, Mohammed A.
    Bozkurt, Ayhan
    Akhtar, Sultan
    Hassan, Muhammad
    CERAMICS INTERNATIONAL, 2021, 47 (06) : 7416 - 7424
  • [48] Synthesis and characterization of porous cobalt oxide/copper oxide nanoplate as novel electrode material for supercapacitors
    Zhang, Shui-rong
    Hu, Zhi-biao
    Liu, Kai-yu
    Liu, Yan-zhen
    He, Fang
    Xie, Qing-liang
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2015, 25 (12) : 4054 - 4062
  • [49] Composite Based on Multi-Walled Carbon Nanotubes and Manganese Oxide with Rhenium Additive for Supercapacitors: Structural and Electrochemical Studies
    Korusenko, Petr M.
    Nesov, Sergey N.
    APPLIED SCIENCES-BASEL, 2022, 12 (24):
  • [50] Hydrothermal Synthesis of Nanostructured Manganese Oxide/Carbon Composites as Electrochemical Capacitors Electrodes
    Guan Hongtao
    Chen Gang
    Wang Yan
    Dong Chengjun
    Wang Yude
    Zhao Heyun
    RARE METAL MATERIALS AND ENGINEERING, 2016, 45 : 1 - 6