A re-examination and partial characterisation of polysaccharides released by mild acid hydrolysis from the chlorite-treated leaves of Sphagnum papillosum

被引:39
作者
Ballance, Simon
Borsheim, Knut Yngve
Inngjerdingen, Kari
Paulsen, Berit Smestad
Christensen, Bjorn E. [1 ]
机构
[1] Norwegian Univ Sci & Technol, NOBIPOL, Dept Biotechnol, NO-7491 Trondheim, Norway
[2] Univ Oslo, Sch Pharm, Dept Pharmacognosy, NO-0316 Oslo, Norway
关键词
5-keto-D-mannuronic acid; sphagnan; Sphagnum moss; peat;
D O I
10.1016/j.carbpol.2006.04.020
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Mild acid hydrolysis was used to release polysaccharides from the chlorite-treated leaves of Sphagnum papillosum. These polysaccharides, collectively known as sphagnan, were physically and chemically characterised. No evidence was found of the presence of a previously described 5-keto-D-mannuronic acid (5-KMA) monomer in sphagnan, or in the chlorite-treated leaves from which sphagnan was extracted. After fractionation by anion-exchange chromatography the majority of polysaccharides were similar to rhamnogalacturonan I-type pectins. They were highly branched and had a weight average molecular weight of 3.9 x 10 g/mol. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:104 / 115
页数:12
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