Influence of stirring speed on the crystallization of calcium carbonate

被引：33

作者：

Yan, Feng-Wen ^{[1
,2
]}

Zhang, Shu-Feng ^{[1
,3
]}

Guo, Cun-Yue ^{[1
]}

Zhang, Xiao-Hui ^{[1
,2
]}

Chen, Guo-Chang ^{[1
]}

Yan, Fang ^{[1
]}

Yuan, Guo-Qing ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci BNLMS, New Mat Lab, Inst Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

[3] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 2009年 / 44卷 / 07期

关键词：

stirring speed; calcium carbonate; crystallization; MORPHOLOGY; MESOCRYSTALS; PRECIPITATION; PARTICLES; CRYSTALS;

D O I：

10.1002/crat.200900190

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Control over crystal morphology of calcium carbonate (CaCO3) was investigated by simply changing the stirring speeds in the process of CaCO3 formation. Scanning electron microscopy (SEM) and powder X-ray diffraction (XRD) measurements explore the morphology evolution of CaCO3 at varying stirring speeds. As the stirring speeds increase, rhombohedral oalcite, spherical vaterite, and monoclinic crystal with coexistence of calcite phase and vaterite phase were formed, suggesting a facile control over calcium carbonate crystallization in constructing crystals with desired morphology. Moreover, almost pure vaterite spherical particles of narrow particle size distribution were formed at optimum. stirring speed. Finally, also elucidated in this work is the mechanism investigation into the construction of various crystal forms via this simple route. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：725 / 728

页数：4

共 25 条

[1]

Antonietti M, 1998, CHEM-EUR J, V4, P2493, DOI 10.1002/(SICI)1521-3765(19981204)4:12<2493::AID-CHEM2493>3.0.CO

[2]

2-V

[3] Mesocrystals:: Inorganic superstructures made by highly parallel crystallization and controlled alignment [J].

Cölfen, H ;

Antonietti, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (35) :5576-5591

[4] Crystal design of calcium carbonate microparticles using double-hydrophilic block copolymers [J].

Colfen, H ;

Antonietti, M .

LANGMUIR, 1998, 14 (03) :582-589

[5] The overgrowth of calcium carbonate on poly(vinyl chloride-co-vinyl acetate-co-maleic acid) [J].

Dalas, E ;

Klepetsanis, P ;

Koutsoukos, PG .

LANGMUIR, 1999, 15 (23) :8322-8327

[6] Control of calcite crystal morphology by a peptide designed to bind to a specific surface [J].

DeOliveira, DB ;

Laursen, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (44) :10627-10631

[7] At the interface of organic and inorganic chemistry: Bioinspired synthesis of composite materials [J].

Estroff, LA ;

Hamilton, AD .

CHEMISTRY OF MATERIALS, 2001, 13 (10) :3227-3235

[8] Crystallization in a mixture of solvents by using a crystal modifier:: Morphology control in the synthesis of highly monodisperse CaCO3 microspheres [J].

Guo, Xiao-Hui ;

Yu, Shu-Hong ;

Cai, Guo-Bing .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (24) :3977-3981

[9] CRYSTALLIZATION OF INORGANIC-COMPOUNDS IN POLYMER-SOLUTIONS .1. CONTROL OF SHAPE AND FORM OF CALCIUM-CARBONATE [J].

KAWAGUCHI, H ;

HIRAI, H ;

SAKAI, K ;

SERA, S ;

NAKAJIMA, T ;

EBISAWA, Y ;

KOYAMA, K .

COLLOID AND POLYMER SCIENCE, 1992, 270 (12) :1176-1181

[10] Effect of inorganic anions on the morphology and structure of magnesium calcite [J].

Kralj, D ;

Kontrec, J ;

Brecevic, L ;

Falini, G ;

Nöthig-Laslo, V .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (07) :1647-1656

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