New Topology in Azide-Bridged Cobalt(II) Complexes: the Weak Ferromagnet [Co2(N3)4(Hexamethylenetetramine)(H2O)]n

被引:24
|
作者
Mautner, Franz A. [2 ]
Oehrstroem, Lars [3 ]
Sodin, Beate [2 ]
Vicente, Ramon [1 ]
机构
[1] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain
[2] Graz Univ Technol, Inst Phys & Theoret Chem, A-8010 Graz, Austria
[3] Chalmers Tekniska Hogskola, Dept Biol & Chem Engn, SE-41296 Gothenburg, Sweden
基金
瑞典研究理事会;
关键词
TO-END AZIDE; CAMBRIDGE STRUCTURAL DATABASE; MAGNETIC-PROPERTIES; RETICULAR CHEMISTRY; CRYSTAL-STRUCTURE; CHAIN COMPOUNDS; MN-II; FRAMEWORKS; NETWORKS; DESIGN;
D O I
10.1021/ic9005373
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The new polynuclear azido-bridged Co(II) compound with formula [Co-2(N-3)(4)(HMTA)(H2O)](n). (1)(HMTA = hexamethylenetetramine) shows a complex 3D structure. To best understand the structure, a network analysis for 1 as bulk compound and also an analysis of the magnetic network has been made, emerging with a new network topology.
引用
收藏
页码:6280 / 6286
页数:7
相关论文
共 50 条
  • [31] Dielectric properties of Co(CO3)(H2O)2(C3H4N2)2 and [Co(C3H3N2)2]n
    Swiatek-Tran, B.
    Kolodziej, H. A.
    Vogt, A.
    Tran, V. H.
    RSC ADVANCES, 2015, 5 (13): : 9539 - 9545
  • [32] Synthesis and Crystal Structure of an Azide Bridged Binuclear Zinc(Ⅱ) Dimer Containing Taurine Schiff Base [Zn2(C8H9N2O3S)2·(N3)2·(H2O)2]2·2H2O
    JIANG Yi-Mina② LI Jia-Minga XIE Fu-Qingb WANG Yan-Feib a(Department of Chemistry and Chemical Engineering
    Chinese Journal of Structural Chemistry, 2006, (07) : 767 - 770
  • [33] Synthesis, crystal structure and magnetic properties of the cobalt(II) chain [Co(bipym)(H2O)2](NO3)2 and the dinuclear compounds [Co2(bipym)3(H2O)4](NO3)4•2H2O and [Co2(bipym)3(H2O)2(SO4)2]•12H2O
    De Munno, G
    Poerio, T
    Julve, M
    Lloret, F
    Viau, G
    NEW JOURNAL OF CHEMISTRY, 1998, 22 (03) : 299 - 305
  • [34] Magneto-structural studies of two new cobalt(II)-N,N-diisobutylisoni-cotinamide compounds: [CoLCl2]n and [Co(L)2(H2O)4][CoLBr3]2•2H2O
    Pannu, Ajay Pal Singh
    Kapoor, Pratibha
    Hundal, Geeta
    Kapoor, Ramesh
    Corbella, Montserrat
    Aliaga-Alcalde, Nuria
    Hundal, Maninder Singh
    DALTON TRANSACTIONS, 2011, 40 (46) : 12560 - 12569
  • [35] Polymeric copper(II)-orotato complexes, [(C5H2N2O4)Cu(H2O)2]n
    Ha, TTB
    Larsonneur-Galibert, AM
    Castan, P
    Jaud, J
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1999, 29 (05) : 565 - 569
  • [36] Polymeric copper(II)-orotato complexes, [(C5H2N2O4)Cu(H2O)2]n
    Tam T.B. Ha
    Anne Marie Larsonneur-Galibert
    Paule Castan
    Joel Jaud
    Journal of Chemical Crystallography, 1999, 29 : 565 - 569
  • [37] Reactions of CH3SH and CH3SSCH3 with Gas-Phase Hydrated Radical Anions (H2O)n•-, CO2•-(H2O)n, and O2•-(H2O)n
    Hoeckendorf, Robert F.
    Hao, Qiang
    Sun, Zheng
    Fox-Beyer, Brigitte S.
    Cao, Yali
    Balaj, O. Petru
    Bondybey, Vladimir E.
    Siu, Chi-Kit
    Beyer, Martin K.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 116 (15): : 3824 - 3835
  • [38] Electron transfer reactions of nitromethane, acetaldehyde and benzaldehyde with (H2O)n-, CO2•-(H2O)n, and O2-(H2O)n, n < 110, in the gas phase
    Akhgarnusch, Amou
    Beyer, Martin K.
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2014, 365 : 295 - 300
  • [39] Syntheses, X-ray structures, spectroscopic and magnetic studies of two new polymeric copper(II)) azide complexes;: [Cu(3-ethylpyridine)2(N3)2]n and [Cu(4-ethylpyridine)2(N3)2]n
    Goher, MAS
    Escuer, A
    Abu-Youssef, MAM
    Mautner, FA
    POLYHEDRON, 1998, 17 (23-24) : 4265 - 4273
  • [40] Reactions of Cp*NbCl4 and Cp*TaCl4 with trimethylsilyl-azide, Me3Si-N3.: Molecular structures of the bis(azido)-oxo-bridged complexes [Cp*NbCl(N3)(μ-N3)]2(μ-O) and [Cp*TaCl2(μ-N3)]2(μ-O) (Cp* = pentamethylcyclopentadienyl)
    Herberhold, M
    Goller, A
    Milius, W
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (09): : 1557 - 1565