New Topology in Azide-Bridged Cobalt(II) Complexes: the Weak Ferromagnet [Co2(N3)4(Hexamethylenetetramine)(H2O)]n

被引:24
|
作者
Mautner, Franz A. [2 ]
Oehrstroem, Lars [3 ]
Sodin, Beate [2 ]
Vicente, Ramon [1 ]
机构
[1] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain
[2] Graz Univ Technol, Inst Phys & Theoret Chem, A-8010 Graz, Austria
[3] Chalmers Tekniska Hogskola, Dept Biol & Chem Engn, SE-41296 Gothenburg, Sweden
基金
瑞典研究理事会;
关键词
TO-END AZIDE; CAMBRIDGE STRUCTURAL DATABASE; MAGNETIC-PROPERTIES; RETICULAR CHEMISTRY; CRYSTAL-STRUCTURE; CHAIN COMPOUNDS; MN-II; FRAMEWORKS; NETWORKS; DESIGN;
D O I
10.1021/ic9005373
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The new polynuclear azido-bridged Co(II) compound with formula [Co-2(N-3)(4)(HMTA)(H2O)](n). (1)(HMTA = hexamethylenetetramine) shows a complex 3D structure. To best understand the structure, a network analysis for 1 as bulk compound and also an analysis of the magnetic network has been made, emerging with a new network topology.
引用
收藏
页码:6280 / 6286
页数:7
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