New Topology in Azide-Bridged Cobalt(II) Complexes: the Weak Ferromagnet [Co2(N3)4(Hexamethylenetetramine)(H2O)]n

被引：24

作者：

Mautner, Franz A. ^{[2
]}

Oehrstroem, Lars ^{[3
]}

Sodin, Beate ^{[2
]}

Vicente, Ramon ^{[1
]}

机构：

[1] Univ Barcelona, Dept Quim Inorgan, Barcelona 08028, Spain

[2] Graz Univ Technol, Inst Phys & Theoret Chem, A-8010 Graz, Austria

[3] Chalmers Tekniska Hogskola, Dept Biol & Chem Engn, SE-41296 Gothenburg, Sweden

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 13期

基金：

瑞典研究理事会;

关键词：

TO-END AZIDE; CAMBRIDGE STRUCTURAL DATABASE; MAGNETIC-PROPERTIES; RETICULAR CHEMISTRY; CRYSTAL-STRUCTURE; CHAIN COMPOUNDS; MN-II; FRAMEWORKS; NETWORKS; DESIGN;

D O I：

10.1021/ic9005373

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new polynuclear azido-bridged Co(II) compound with formula [Co-2(N-3)(4)(HMTA)(H2O)](n). (1)(HMTA = hexamethylenetetramine) shows a complex 3D structure. To best understand the structure, a network analysis for 1 as bulk compound and also an analysis of the magnetic network has been made, emerging with a new network topology.

引用

页码：6280 / 6286

页数：7

共 50 条

[1] An azide-bridged homospin single-chain magnet:: [Co(2,2′-bithiazoline)(N3)2]n
Liu, TF
Fu, D
Gao, S
Zhang, YZ
Sun, HL
Su, G
Liu, YJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (46) : 13976 - 13977
[2] The azide-bridged mixed-valent cobalt(II,III) compound [(CH3)3NH]2[CoIICo2III(N3)10]
Liu, Yan-Ju
Li, Yu-Xian
Xu, Min
Wang, Xia
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M27 - U390
[3] Structural and spectroscopic properties of Hexamethylenetetramine cobalt(II) complex:: [Co(NCS)2(hmt)2(H2O)2][Co(NCS)2(H2O)4] (H2O)
Zhang, Y
Li, J
Xu, H
Hou, H
Nishiura, M
Imamoto, T
JOURNAL OF MOLECULAR STRUCTURE, 1999, 510 (1-3) : 191 - 196
[4] Synthesis and Crystal Structures of the Mixed Ligand Coordination Polymers [Co2(N3)2(BZA)4(H2O)]·EtOH, Cu(N3)(BZA)2(H2O), and Cu(N3)(SUCC)(H2O)2 (N3 = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene, BZA = benzoate, and SUCC = succinate)
Rachel C. Severance
Mark D. Smith
Shae Anne Vaughn
LeRoy Peterson
Hans-Conrad zur Loye
Journal of Chemical Crystallography, 2012, 42 : 141 - 149
[5] Synthesis and Crystal Structures of the Mixed Ligand Coordination Polymers [Co2(N3)2(BZA)4(H2O)]•EtOH, Cu(N3)(BZA)2(H2O), and Cu(N3)(SUCC)(H2O)2 (N3=1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene, BZA = benzoate, and SUCC = succinate)
Severance, Rachel C.
Smith, Mark D.
Vaughn, Shae Anne
Peterson, LeRoy, Jr.
zur Loye, Hans-Conrad
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2012, 42 (02) : 141 - 149
[6] ISOSTRUCTURAL COBALT(II) AND ZINC(II) COMPLEXES OF THE N,N-BIS(CARBOXYMETHYL)-BETA-ALANINATO(3-) ION - CRYSTAL-STRUCTURE OF THE COBALT(II) DERIVATIVE, [CO(H2O)6][CO2L2(H2O)2].4H2O
PEREZ, JMG
GUTIERREZ, JN
DUNG, NH
VIOSSAT, B
BUSNOT, A
WINTENBERGER, M
INORGANICA CHIMICA ACTA, 1991, 184 (02) : 243 - 249
[7] Syntheses and structural characterization of two nitrilotriacetate cobalt complexes:: [{CoK2(NTA)(Hmta)(H2O)3}NO3]n and [{Co(4,4′-bpy)2(H2O)4}{Co2(NTA)2(4,4′-bpy)(H2O)2}]
Chen, ZL
Liang, FP
Tang, XF
Chen, MS
Song, LH
Hu, RX
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (15): : 3092 - 3095
[8] M2(N3)4(hmt)(H2O) (M = Co2+ and Ni2+, hmt = hexamethylenetetramine): mixed azide-hmt bridged 3D metal frameworks with long-range magnetic ordering
Li, Ru-Yin
Wang, Zhe-Ming
Gao, Song
CRYSTENGCOMM, 2009, 11 (10): : 2096 - 2101
[9] New copper(II) and cobalt(II) complexes with the N,N′-bis(antipyryl-4-methyl)-piperazine (BAMP) ligand:: [Co2(BAMP)Cl4 and [Cu(BAMP)(H2O)(ClO4)2
Costisor, O
Pantenburg, I
Tudose, R
Meyer, G
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2004, 630 (11): : 1645 - 1649
[10] Coordination polymers of cobalt(II):: [Co(4,4′-bpy)2(O2CCF3)2]n and [Co(4,4′-bpy)(O2CCH3)2(H2O)2]n
Zhang, YS
Enright, GD
Breeze, SR
Wang, SN
NEW JOURNAL OF CHEMISTRY, 1999, 23 (06) : 625 - 628

← 1 2 3 4 5 →