Valorization of agro-industrial by-products: analysis of biodiesel production from porcine fat waste

被引:18
|
作者
Skoronski, Everton [1 ]
de Oliveira, Daiana Cardoso [2 ]
Fernandes, Mylena [1 ]
da Silva, Gustavo Felippe [3 ]
Borba Magalhaes, Maria de Lourdes [3 ]
Joao, Jair Juarez [2 ]
机构
[1] Univ Estado Santa Catarina, Dept Engn Ambiental, Ctr Ciencias Agrovet, Lab Tratamento Aguas & Residuos, BR-88520000 Lages, SC, Brazil
[2] Univ Sul Santa Catarina, Ctr Tecnol, Grp Pesquisas Catalise Enzimat & Sintese Organ, BR-88704900 Tubarao, SC, Brazil
[3] Univ Estado Santa Catarina, Ctr Ciencias Agrovet, Dept Prod Anim & Alimentos, Lab Tecnol Enzimat, BR-88520000 Lages, SC, Brazil
关键词
Biodiesel; Porcine fat waste; Waste-to-energy; Enzyme; Lipase; SOYBEAN OIL; ACID; ESTERIFICATION; CATALYST; LIPASE; ESTERS;
D O I
10.1016/j.jclepro.2015.10.026
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Recycling of residual animal fat from industrial meat processing for biodiesel production is an attractive alternative, since provides a renewable energy source and minimizes environmental impact of waste disposal. In this work, we propose a valorization strategy of rendering facilities animal fat by investigation of the optimal parameters for ester production using chemical as well as enzymatic catalysis. Although transesterification reactions for biodiesel production have been previously reported, this is the first report of ester production using waste derived animal fat as substrate. The best-obtained yield for chemical catalysis was 90.72-95.76% conversion using alcohol: potassium hydroxide molar ratios ranging from 1:5 to 1:7. For enzymatic catalysis using commercial lipases, obtained yields were 99.77% using methanol and 76.04% using ethanol as substrates. We have also shown here the feasibility of enzymatic catalysis using immobilized lipases. Catalysis using immobilized enzymes produced the best yields, which is advantageous since enzyme can be directly separated from reaction mixture, yielding cleaner products and allowing enzyme recycling. The valorization strategy presented here can be applied for waste recycling of animal fat in meat processing industries. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2553 / 2559
页数:7
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