The first electrochemical sensor for determination of mangiferin based on an ionic liquid-graphene nanosheets paste electrode

被引:115
作者
Tajik, Somayeh [1 ,2 ]
Taher, Mohammad Ali [1 ]
Beitollahi, Hadi [3 ]
机构
[1] Shahid Bahonar Univ Kerman, Dept Chem, Kerman, Iran
[2] Shahid Bahonar Univ Kerman, Young Researchers Soc, Kerman, Iran
[3] Grad Univ Adv Technol, Inst Sci & High Technol & Environm Sci, Dept Environm, Kerman, Iran
关键词
Mangiferin; Graphene nanosheets; Modified electrode; Voltammetry; SELECTIVE VOLTAMMETRIC DETERMINATION; URIC-ACID; CARBON NANOTUBES; 2,7-BIS(FERROCENYL ETHYL)FLUOREN-9-ONE; ASCORBIC-ACID; L-CYSTEINE; OXIDATION; BEHAVIOR; NANOPARTICLES; NORATHYRIOL;
D O I
10.1007/s11581-013-1063-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel carbon paste electrode modified with graphene nanosheets and an ionic liquid (n-hexyl-3-methylimidazolium hexafluoro phosphate) was fabricated and used for the electrochemical study of mangiferin for the first time. This modified electrode offers a considerable improvement in voltammetric sensitivity toward mangiferin, compared to the bare electrode. Square wave voltammetry (SWV) exhibits a linear dynamic range from 5.0 x 10(-8) to 2.0 x 10(-4) M and a detection limit of 20.0 nM for mangiferin. Finally, the proposed method was successfully applied to the determination of mangiferin in real samples such as serum and urine.
引用
收藏
页码:1155 / 1161
页数:7
相关论文
共 48 条
[1]   A selective sensor for nanolevel detection of lead (II) in hazardous wastes using ionic-liquid/Schiff base/MWCNTs/nanosilica as a highly sensitive composite [J].
Afkhami, Abbas ;
Madrakian, Tayyebeh ;
Shirzadmehr, Ali ;
Bagheri, Hasan ;
Tabatabaee, Masoumeh .
IONICS, 2012, 18 (09) :881-889
[2]  
[Anonymous], 2001, ELECTROCHEMICAL METH
[3]   Electrochemical sensing of NADH on NiO nanoparticles-modified carbon paste electrode and fabrication of ethanol dehydrogenase-based biosensor [J].
Aydogdu, Gozde ;
Zeybek, Derya Koyuncu ;
Zeybek, Bulent ;
Pekyardimci, Sule .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2013, 43 (05) :523-531
[4]   New electrodes for old: from carbon nanotubes to edge plane pyrolytic graphite [J].
Banks, CE ;
Compton, RG .
ANALYST, 2006, 131 (01) :15-21
[5]   Benzoylferrocene-modified carbon nanotubes paste electrode as a voltammetric sensor for determination of hydrochlorothiazide in pharmaceutical and biological samples [J].
Beitollahi, Hadi ;
Ghorbani, Farzaneh .
IONICS, 2013, 19 (11) :1673-1679
[6]   New voltammetric strategy for simultaneous determination of norepinephrine, acetaminophen, and folic acid using a 5-amino-3',4'-dimethoxy-biphenyl-2-ol/carbon nanotube paste electrode [J].
Beitollahi, Hadi ;
Mohadesi, Alireza ;
Mahani, Saeedeh Khalilizadeh ;
Karimi-Maleh, Hassan ;
Akbari, Ali .
IONICS, 2012, 18 (07) :703-710
[7]   Electroanalysis and Simultaneous Determination of 6-Thioguanine in the Presence of Uric Acid and Folic Acid Using a Modified Carbon Nanotube Paste Electrode [J].
Beitollahi, Hadi ;
Raoof, Jahan-Bakhsh ;
Hosseinzadeh, Rahman .
ANALYTICAL SCIENCES, 2011, 27 (10) :991-997
[8]   Application of a Carbon-Paste Electrode Modified with 2,7-Bis(ferrocenyl ethyl)fluoren-9-one and Carbon Nanotubes for Voltammetric Determination of Levodopa in the Presence of Uric Acid and Folic Acid [J].
Beitollahi, Hadi ;
Raoof, Jahan-Bakhsh ;
Hosseinzadeh, Rahman .
ELECTROANALYSIS, 2011, 23 (08) :1934-1940
[9]   Powdered activated carbon and carbon paste electrodes: comparison of electrochemical behaviour [J].
Biniak, S. ;
Pakula, M. ;
Darlewski, W. ;
Swiatkowski, A. ;
Kula, P. .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2009, 39 (05) :593-600
[10]   Electrocatalytic amperometric determination of amitrole using a cobalt-phthalocyanine-modified carbon paste electrode [J].
Chicharro, M ;
Zapardiel, A ;
Bermejo, E ;
Moreno, M ;
Madrid, E .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2002, 373 (4-5) :277-283