A highly selective PET-based chemosensor for instant detecting of Zn2+

被引:30
作者
Guan, Jie [1 ]
Zhang, Peng [1 ]
Wei, Tai-bao [1 ]
Lin, Qi [1 ]
Yao, Hong [1 ]
Zhang, You-ming [1 ]
机构
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Minist Educ China, Key Lab Ecoenvironm Related Polymer Mat,Key Lab P, Lanzhou 730070, Gansu, Peoples R China
基金
中国国家自然科学基金;
关键词
AQUEOUS-SOLUTION; LIVING CELLS; FLUORESCENCE PROBE; EXCIMER FORMATION; ZINC-DEFICIENCY; METAL-IONS; ZN(II); SENSOR; WATER; COMPLEX;
D O I
10.1039/c4ra04130e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple Zn2+-selective chemosensor system based on acylhydrazone was designed and synthesized, which could detect Zn2+ ions in aqueous solution with high selectivity and sensitivity over a wide pH range by the mechanism of photo-induced electron transfer (PET). The obvious color changes and pronounced OFF-ON-type fluorescent signaling behavior can be seen by the naked eye. The detection limit of L2 for Zn2+ ion was as low as 0.13 mu M. In addition, L2-Zn2+ complex can be used as an ON-OFF chemosensor candidate for Cu2+, as the Zn2+-induced emission can be quenched upon addition of Cu2+. Moreover, test strips for Zn2+ based on L2 were also fabricated, which could be used as a convenient and efficient test kit for instantly detecting Zn2+ in aqueous solution.
引用
收藏
页码:35797 / 35802
页数:6
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