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A highly selective PET-based chemosensor for instant detecting of Zn2+
被引:30
作者:
Guan, Jie
[1
]
Zhang, Peng
[1
]
Wei, Tai-bao
[1
]
Lin, Qi
[1
]
Yao, Hong
[1
]
Zhang, You-ming
[1
]
机构:
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Minist Educ China, Key Lab Ecoenvironm Related Polymer Mat,Key Lab P, Lanzhou 730070, Gansu, Peoples R China
来源:
基金:
中国国家自然科学基金;
关键词:
AQUEOUS-SOLUTION;
LIVING CELLS;
FLUORESCENCE PROBE;
EXCIMER FORMATION;
ZINC-DEFICIENCY;
METAL-IONS;
ZN(II);
SENSOR;
WATER;
COMPLEX;
D O I:
10.1039/c4ra04130e
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A simple Zn2+-selective chemosensor system based on acylhydrazone was designed and synthesized, which could detect Zn2+ ions in aqueous solution with high selectivity and sensitivity over a wide pH range by the mechanism of photo-induced electron transfer (PET). The obvious color changes and pronounced OFF-ON-type fluorescent signaling behavior can be seen by the naked eye. The detection limit of L2 for Zn2+ ion was as low as 0.13 mu M. In addition, L2-Zn2+ complex can be used as an ON-OFF chemosensor candidate for Cu2+, as the Zn2+-induced emission can be quenched upon addition of Cu2+. Moreover, test strips for Zn2+ based on L2 were also fabricated, which could be used as a convenient and efficient test kit for instantly detecting Zn2+ in aqueous solution.
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页码:35797 / 35802
页数:6
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