Two 1D Ladderlike Heterometallic Zinc(II) Coordination Polymers: Syntheses, Crystal Structures, and Fluorescence Properties

被引：2
作者：
Zheng, Yan-Feng [1 ]
Sun, Ya-Qiu [1 ]
Liu, Xiao-Xu [1 ]
Xu, Yan-Yan [1 ]
Gao, Dong-Zhao [1 ]
Zhang, Guo-Ying [1 ]
机构：
[1] Tianjin Normal Univ, Tianjin Key Lab Struct & Performance Funct Mol, Key Lab Inorgan Organ Hybrid Funct Mat Chem, Minist Educ,Coll Chem, Tianjin 300387, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 11期
基金：
中国国家自然科学基金;
关键词：
Macrocyclic oxamide complexes; Zinc; Crystal structure; Fluorescence; Heterometallic coordination polymers; METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; HETERONUCLEAR COMPLEXES; MACROCYCLIC OXAMIDE; LIGANDS; AZIDO; 3D; CU; CU(PYAC)(2); CLUSTERS;
D O I：
10.1002/zaac.201400162
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two coordination polymers [Zn-2(ipt)(2)(CuL)(2)(H2O)] (1) and [Zn-2(ipt)(2)(NiL)(2)(H2O)] (2) (ML, H2L = 2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-dien; H(2)ipt = isophthalic acid) were synthesized by solvothermal methods and characterized by single-crystal X-ray diffraction. Complexes 1 and 2 exhibit ladderlike chains, consisting of Zn4Cu4 and Zn4Ni4 units, respectively, which are connected via oxamide and isophthalate. These chains are further interlinked by hydrogen bonds resulting in a 2D supramolecular architecture. The fluorescence properties of compounds 1 and 2 are also discussed.
引用
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页码：2232 / 2237
页数：6
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