Palladium-catalyzed intramolecular Cp-H bond functionalization/arylation: an enantioselective approach to planar chiral quinilinoferrocenes

被引：64

作者：

Ma, Xinna ^{[1
]}

Gu, Zhenhua ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

来源：

RSC ADVANCES | 2014年 / 4卷 / 68期

关键词：

TRANSITION-METAL-COMPLEXES; ASYMMETRIC CATALYSIS; FERROCENE DERIVATIVES; ARENE CHROMIUM; HECK REACTION; LIGANDS; METALLOCENES; METHOXYCARBONYLATION; DESYMMETRIZATION; HETEROCYCLES;

D O I：

10.1039/c4ra07832b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A palladium-catalyzed intramolecular asymmetric Cp-H functionalization/cyclization reaction to construct planar chiral quinilinoferrocenes was reported. The current investigation indicated that Carriera's O-PINAP ligands gave the best enantiomeric induction. The palladium-catalyzed reaction allowed a variety of chiral quinilinoferrocenes to be synthesized with broad functional group tolerance.

引用

页码：36241 / 36244

页数：4

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