Organic-inorganic mixed-valence systems with strongly-coupled triarylamine and cyclometalated osmium

被引：24
|
作者：
Nie, Hai-Jing [1 ]
Shao, Jiang-Yang [1 ]
Yao, Chang-Jiang [1 ]
Zhong, Yu-Wu [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 70期
基金：
中国国家自然科学基金;
关键词：
CHARGE-TRANSFER IVCT; ELECTRON-TRANSFER; ELECTROPOLYMERIZED FILMS; DINUCLEAR COMPLEXES; RUTHENIUM; TRANSITION; COMMUNICATION; DISTANCE; LIGANDS;
D O I：
10.1039/c4cc04268a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Organic-inorganic mixed-valence systems with strongly-coupled triarylamine and cyclometalated osmium have been developed. They display two well-separated redox couples at low potentials. Each of the three readily accessible oxidation states can be distinguished by the absorbance at three different wavelengths.
引用
收藏
页码：10082 / 10085
页数：4
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