Cyclohexane Oxidation Over Size-Uniform Au Nanoparticles (SBA-15 hosted) in a Continuously Stirred Tank Reactor Under Mild Conditions

被引：33
作者：
Li, Li [1 ]
Jin, Chen [1 ]
Wang, Xiaochen [1 ]
Ji, Weijie [1 ]
Pan, Yi [1 ]
van der Knaap, Theo [2 ]
van der Stoel, Roland [2 ]
Au, C. T. [3 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Dept Chem, MOE,Key Lab Mesoscop Chem, Nanjing 210093, Peoples R China
[2] DSM Fibre Intermediates, NL-6130 AA Sittard, Netherlands
[3] Hong Kong Baptist Univ, Dept Chem, Kowloon, Hong Kong, Peoples R China
来源：
CATALYSIS LETTERS | 2009年 / 129卷 / 3-4期
关键词：
Mesoporous material; Gold; Nanostructure; Oxidation; Cyclohexane; HIGHLY EFFICIENT OXIDATION; REDOX MOLECULAR-SIEVES; GOLD NANOPARTICLES; SELECTIVE OXIDATION; MESOPOROUS SILICA; AEROBIC OXIDATION; CATALYST; OXYGEN; MECHANISM; AIR;
D O I：
10.1007/s10562-009-9853-x
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cyclohexane oxidation was operated in a continuously stirred tank reactor at system pressures of 0.6-1.0 MPa under an air-like O-2/N-2 atmosphere (rather than pure O-2). Catalytic performance was investigated over Au nanoparticles (size: 3-8 nm) hosted by SBA-15 as well as Au particles (> 60 nm) deposited on MCM-41, and high turnover frequencies of desired products were detected over the former. Based on intrinsic activities of representative catalysts, we derived a size-sensitivity feature of cyclohexane oxidation over Au particles.
引用
收藏
页码：303 / 311
页数：9
相关论文
共 30 条
  • [1] Catalyst parameters determining activity and selectivity of supported gold nanoparticles for the aerobic oxidation of alcohols:: The molecular reaction mechanism
    Abad, Alberto
    Corma, Avelino
    Garcia, Hermenegildo
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (01) : 212 - 222
  • [2] Investigations on gold nanoparticles in mesoporous and microporous materials
    Akolekar, DB
    Bhargava, SK
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 236 (1-2) : 77 - 86
  • [3] Oxidative transformations of organic compounds mediated by redox molecular sieves
    Arends, IWCE
    Sheldon, RA
    Wallau, M
    Schuchardt, U
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (11) : 1144 - 1163
  • [4] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES
    BECK, JS
    VARTULI, JC
    ROTH, WJ
    LEONOWICZ, ME
    KRESGE, CT
    SCHMITT, KD
    CHU, CTW
    OLSON, DH
    SHEPPARD, EW
    MCCULLEN, SB
    HIGGINS, JB
    SCHLENKER, JL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10834 - 10843
  • [5] Mesoporous redox molecular sieves analogous to MCM-41
    Carvalho, WA
    Varaldo, PB
    Wallau, M
    Schuchardt, U
    [J]. ZEOLITES, 1997, 18 (5-6): : 408 - 416
  • [6] Gold nanoparticles and gold(III) complexes as general and selective hydrosilylation catalysts
    Corma, Avelino
    Gonzalez-Arellano, Camino
    Iglesias, Marta
    Sanchez, Felix
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (41) : 7820 - 7822
  • [7] FALSIG H, 2005, ANGEW CHEM INT EDIT, V47, P4835
  • [8] Effective catalysis of simple metalloporphyrins for cyclohexane oxidation with air in the absence of additives and solvents
    Guo, CC
    Chu, MF
    Liu, Q
    Liu, Y
    Guo, DC
    Liu, XQ
    [J]. APPLIED CATALYSIS A-GENERAL, 2003, 246 (02) : 303 - 309
  • [9] Studies of simple μ-oxo-bisiron(III)porphyrin as catalyst of cyclohexane oxidation with air in absence of cocatalysts or coreductants
    Guo, CC
    Liu, XQ
    Liu, Y
    Liu, Q
    Chu, MF
    Zhang, XB
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 192 (1-2) : 289 - 294
  • [10] A new evidence of the high-valent oxo-metal radical cation intermediate and hydrogen radical abstract mechanism in hydrocarbon hydroxylation catalyzed by metalloporphyrins
    Guo, CC
    Song, JX
    Chen, XB
    Jiang, GF
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 157 (1-2) : 31 - 40
123