Dod-S-Me and methyl 6-morpholinohexyl sulfide (MMS) as new odorless borane carriers

被引:22
作者
Patra, PK [1 ]
Nishide, K [1 ]
Fuji, K [1 ]
Node, M [1 ]
机构
[1] Kyoto Pharmaceut Univ, Dept Pharmaceut Mfg Chem, Yamashina, Kyoto 6078414, Japan
来源
SYNTHESIS-STUTTGART | 2004年 / 07期
关键词
odorless; sulfides; borane; hydroborations; reductions;
D O I
10.1055/s-2004-822338
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Odorless Dod-S-Me (1) and MMS (3) are developed as efficient borane carriers. The yields of hydroborations and reductions with borane complex 2 of 1 are very high and the recovery of 1 after the reaction is quantitative. The borane complexes 4 and 5 of 3 are also useful. In the latter case chromatographic separation is unnecessary when excess oxidizing agent (alkaline H2O2) is used after hydroboration.
引用
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页码:1003 / 1006
页数:4
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