Dod-S-Me and methyl 6-morpholinohexyl sulfide (MMS) as new odorless borane carriers

被引：22

作者：

Patra, PK ^{[1
]}

Nishide, K ^{[1
]}

Fuji, K ^{[1
]}

Node, M ^{[1
]}

机构：

[1] Kyoto Pharmaceut Univ, Dept Pharmaceut Mfg Chem, Yamashina, Kyoto 6078414, Japan

来源：

SYNTHESIS-STUTTGART | 2004年 / 07期

关键词：

odorless; sulfides; borane; hydroborations; reductions;

D O I：

10.1055/s-2004-822338

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Odorless Dod-S-Me (1) and MMS (3) are developed as efficient borane carriers. The yields of hydroborations and reductions with borane complex 2 of 1 are very high and the recovery of 1 after the reaction is quantitative. The borane complexes 4 and 5 of 3 are also useful. In the latter case chromatographic separation is unnecessary when excess oxidizing agent (alkaline H2O2) is used after hydroboration.

引用

页码：1003 / 1006

页数：4

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