Catalytic conversion of cellulose into sugar alcohols

被引:677
作者
Fukuoka, Atsushi [1 ]
Dhepe, Paresh L. [1 ]
机构
[1] Hokkaido Univ, Catalysis Res Ctr, Kita Ku, Sapporo, Hokkaido 0010021, Japan
关键词
carbohydrates; catalysts; heterogeneous catalysis; reduction; water;
D O I
10.1002/anie.200601921
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Sweetly done: Pt or Ru catalysts supported on inorganic oxides show high activity for the conversion of cellulose into sugar alcohols (mainly sorbitol) in water under hydrogen pressure; furthermore, the catalysts can be recycled over repeated runs. Glucose is produced in low yields, thus suggesting that the Pt (or Ru)/oxide works as a bifunctional catalyst for the hydrolysis of cellulose and subsequent reduction to sugar alcohols. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5161 / 5163
页数:3
相关论文
共 20 条
[1]   Biotechnology for the production of commodity chemicals from biomass [J].
Danner, H ;
Braun, R .
CHEMICAL SOCIETY REVIEWS, 1999, 28 (06) :395-405
[2]   Renewable hydrogen by aqueous-phase reforming of glucose [J].
Davda, RR ;
Dumesic, JA .
CHEMICAL COMMUNICATIONS, 2004, (01) :36-37
[3]  
De Wulf P, 2000, BIOTECHNOL BIOENG, V69, P339, DOI 10.1002/1097-0290(20000805)69:3&lt
[4]  
339::AID-BIT12&gt
[5]  
3.0.CO
[6]  
2-E
[7]   Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas [J].
Dhepe, PL ;
Ohashi, M ;
Inagaki, S ;
Ichikawa, M ;
Fukuoka, A .
CATALYSIS LETTERS, 2005, 102 (3-4) :163-169
[8]  
Fan L. T., 1987, CELLULOSE HYDROLYSIS, DOI DOI 10.1007/978-3-642-72575-3_4
[9]   GLUCOSE HYDROGENATION ON PROMOTED RANEY-NICKEL CATALYSTS [J].
GALLEZOT, P ;
CERINO, PJ ;
BLANC, B ;
FLECHE, G ;
FUERTES, P .
JOURNAL OF CATALYSIS, 1994, 146 (01) :93-102
[10]   Molecular hydrogen-originated protonic acid site as active site on solid acid catalyst [J].
Hattori H. ;
Shishido T. .
Catalysis Surveys from Asia, 1997, 1 (2) :205-213