High-pressure NMR spectroscopy: Some general aspects and applications

被引:3
作者
Sprengers, JW [1 ]
Kluwer, AM [1 ]
Gaemers, S [1 ]
Elsevier, CJ [1 ]
机构
[1] Univ Amsterdam, Inst Mol Chem Coordinat & Organomet Chem, NL-1018 WV Amsterdam, Netherlands
来源
HIGH PRESSURE EFFECTS IN CHEMISTRY, BIOLOGY AND MATERIALS SCIENCE | 2002年 / 208-2卷
关键词
compressed fluids; gas-liquid systems; high pressures; homogeneous catalysis; NMR spectroscopy; organometallic chemistry; supercritical fluids;
D O I
10.4028/www.scientific.net/DDF.208-209.283
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
High-pressure NMR has been applied to numerous problems in science. This paper deals with the development of the instrumentation needed for high-pressure NMR experiments and with selected Applications of this powerful technique. High-pressure NMR spectroscopy in compressed fluids, in gas-liquid systems and in supercritical fluids will be discussed. Among other items, the relation to homogenous catalysis and organometallic chemistry will be highlighted.
引用
收藏
页码:283 / 294
页数:12
相关论文
共 57 条
  • [1] AKASAKA K, 2001, METHODS ENZYMOLOGY N
  • [2] [Anonymous], 1986, INORGANIC HIGH PRESS
  • [3] A new high pressure sapphire nuclear magnetic resonance cell
    Bai, S
    Taylor, CM
    Mayne, CL
    Pugmire, RJ
    Grant, DM
    [J]. REVIEW OF SCIENTIFIC INSTRUMENTS, 1996, 67 (01) : 240 - 243
  • [4] NUCLEAR MAGNETIC RESONANCE IN LIQUIDS UNDER HIGH PRESSURE
    BENEDEK, GB
    PURCELL, EM
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1954, 22 (12) : 2003 - 2012
  • [5] Mimicking the HDS activity of promoted tungsten catalysts. A homogeneous modeling study using a two-component tungsten/rhodium system
    Bianchini, C
    Jimenez, MV
    Meli, A
    Moneti, S
    Patinec, V
    Vizza, F
    [J]. ORGANOMETALLICS, 1997, 16 (26) : 5696 - 5705
  • [6] The slowest water exchange at a homoleptic mononuclear metal center: Variable-temperature and variable-pressure O-17 NMR study on [Ir(H2O)(6)](3+)
    Cusanelli, A
    Frey, U
    Richens, DT
    Merbach, AE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (22) : 5265 - 5271
  • [7] Cusanelli T., 1997, SPECTROSC EUR, V9, P22
  • [8] Fluorocarbons dissolved in supercritical carbon dioxide. NMR evidence for specific solute-solvent interactions
    Dardin, A
    DeSimone, JM
    Samulski, ET
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (10): : 1775 - 1780
  • [9] INFLUENCE OF LIGANDS AND ANIONS ON THE RATE OF CARBON-MONOXIDE INSERTION INTO PALLADIUM METHYL BONDS IN THE COMPLEXES (P-P)PD(CH3)CL AND [(P-P)PD(CH3)(L)]+SO3CF3- (P-P = DPPE, DPPP, DPPB, DPPF, L = CH3CN, PPH3)
    DEKKER, GPCM
    ELSEVIER, CJ
    VRIEZE, K
    VANLEEUWEN, PWNM
    [J]. ORGANOMETALLICS, 1992, 11 (04) : 1598 - 1603
  • [10] DUCOMMUN Y, 1986, INORGANIC HIGH PRESS, pCH2