Particle configuration and properties of poly(vinyl chloride)/halloysite nanotubes nanocomposites via in situ suspension polymerization

被引：15
作者：
Liu, Cong [1 ]
Luo, Yuanfang [2 ]
Jia, Zhixin [2 ]
Li, Shuangquan [3 ]
Huang, Dong [4 ]
Jia, Demin [2 ]
机构：
[1] S China Normal Univ, Sch Chem & Environm, Inst Mat Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China
[2] S China Univ Technol, Sch Mat Sci & Engn, Inst High Performance Rubber & Nanocomposites, Guangzhou 510640, Guangdong, Peoples R China
[3] XinJiang Tianye Grp Co Ltd, Xinjiang 832012, Shihezi, Peoples R China
[4] XinJiang Zhongfa Chem Co Ltd, Xinjiang 832012, Shihezi, Peoples R China
来源：
POLYMER COMPOSITES | 2014年 / 35卷 / 05期
关键词：
THERMAL-PROPERTIES; COMPOSITES;
D O I：
10.1002/pc.22729
中图分类号：
TB33 [复合材料];
学科分类号：
摘要：
Poly(vinyl chloride) (PVC)/halloysite nanotubes (HNTs) nanocomposites were synthesized by in situ suspension polymerization of vinyl chloride (VC) in the presence of HNTs. The microstructure, mean particle size, and cold plasticizer absorption (CPA) of these resins and the rheological property, mechanical properties and thermal properties of PVC/HNTs nanocomposites were investigated. The results show that the mean particle size, the degree of porosity, and the CPA of PVC resins decrease with the addition of HNTs. The plasticization time and the equilibrium torque of PVC/HNTs nanocomposites are found to be longer and higher than that for the neat PVC. HNTs are uniformly distributed in the PVC matrix and effective in toughening and stiffening PVC nanocomposites when the addition of HNTs is 4.0 wt% or less. The glass transition temperatures of the PVC/HNTs nanocomposites were nearly identical to that of pure PVC. POLYM. COMPOS., 35:856-863, 2014. (c) 2013 Society of Plastics Engineers
引用
收藏
页码：856 / 863
页数：8
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