Nucleation kinetics of vapor bubbles in a liquid with arbitrary viscosity

被引:7
作者
Alekseechkin, Nikolay V. [1 ]
机构
[1] Kharkov Phys & Technol Inst, Natl Sci Ctr, Akhiezer Inst Theoret Phys, UA-61108 Kharkov, Ukraine
关键词
1ST-ORDER PHASE-TRANSITIONS; REPLACEMENT FREE-ENERGY; HOMOGENEOUS NUCLEATION; CHEMICAL-REACTIONS; MIXING ENTROPY; VOLUME SCALE; HELIUM; CAVITATION; PRESSURE; CLUSTERS;
D O I
10.1140/epjb/e2013-40547-7
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The multivariable theory of nucleation in Langevin's approach [N.V. Alekseechkin, J. Chem. Phys. 124, 124512 (2006); N.V. Alekseechkin, J. Chem. Phys. 129, 024512 (2008)] is applied to the problem of vapor bubbles formation in a liquid with arbitrary viscosity. The obtained expression for the nucleation rate of bubbles is valid for arbitrary relations between the kinetic parameters controlling the nucleation process: viscosity, inertia of a liquid, the rate of evaporation into a bubble and the rate of heat exchange between the bubble and ambient liquid. So, the presented theory yields a complete description of the vapor-bubbles nucleation kinetics in single-component liquids. Limiting cases with respect to the mentioned parameters are considered, in particular, the low-viscosity limit. It is shown that the low-and high-viscosity nucleation rates differ from each other qualitatively and quantitatively. The possibility of application of the theory to cavitation in superfluid helium-4 is discussed.
引用
收藏
页码:390 / 403
页数:11
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