Solvent-Free Synthesis of CuO/HKUST-1 Composite and Its Photocatalytic Application

被引：63

作者：

Jin, Ming ^{[1
]}

Ban, Xuefeng ^{[2
]}

Gao, Junkuo ^{[2
]}

Chen, Jihua ^{[3
]}

Hensley, Dale K. ^{[3
]}

Ho, Hoi Chun ^{[3
]}

Percoco, Rebecca J. ^{[4
]}

Ritzi, Christopher M. ^{[4
]}

Yue, Yanfeng ^{[4
]}

机构：

[1] Qufu Normal Univ, Coll Chem & Chem Engn, Qufu 273165, Shandong, Peoples R China

[2] Zhejiang Sci Tech Univ, Coll Mat & Text, Key Lab Adv Text Mat & Mfg Technol, Inst Fiber Based New Energy Mat,Minist Educ, Hangzhou 310018, Zhejiang, Peoples R China

[3] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA

[4] Sul Ross State Univ, Dept Biol Geol & Phys Sci, Alpine, TX 79832 USA

来源：

INORGANIC CHEMISTRY | 2019年 / 58卷 / 13期

关键词：

METAL-ORGANIC FRAMEWORK; SOLAR HYDROGEN-PRODUCTION; VISIBLE-LIGHT-RESPONSE; SRTIO3; PHOTOCATALYSTS; OXIDE COMPOSITES; MOF; ADSORPTION; CAPTURE; CO2; FABRICATION;

D O I：

10.1021/acs.inorgchem.9b00362

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A metal-organic framework (MOF) is one kind of crystalline microporous material and is increasingly used as a host of catalytically active guests. Nanostructured materials supported on MOFs have presented enhanced catalytic activity and stability. Templates or several steps are essential to the synthesis of MOF composites. Simple and effective MOF synthesis methods are still challenging. Nanosized copper oxide particles in MOF composites, described as nanosized CuO@HKUST-1, were prepared by a facile solvent-free reaction. These series of CuO@HKUST-1 composites exhibited excellent photocatalytic activity for production of hydrogen and methylene blue (MB) degradation under visible light. This synthesis method provides an effective way to fabricate MOF-related nanocomposite catalysts.

引用

页码：8332 / 8338

页数：7

共 50 条

[1] Tuning MOF CO2 Adsorption Properties via Cation Exchange [J].

An, Jihyun ;

Rosi, Nathaniel L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (16) :5578-+

[2] EPR and FT-IR spectroscopic studies of Bi2O3-B2O3-CuO glasses [J].

Ardelean, I. ;

Cora, Simona ;

Rusu, Dorina .

PHYSICA B-CONDENSED MATTER, 2008, 403 (19-20) :3682-3685

[3] Self-templated synthesis of nanoporous CdS nanostructures for highly efficient photocatalytic hydrogen production under visible [J].

Bao, Ningzhong ;

Shen, Liming ;

Takata, Tsuyoshi ;

Domen, Kazunari .

CHEMISTRY OF MATERIALS, 2008, 20 (01) :110-117

[4] Dual-Emitting MOF⊃Dye Composite for Ratiometric Temperature Sensing [J].

Cui, Yuanjing ;

Song, Ruijing ;

Yu, Jiancan ;

Liu, Min ;

Wang, Ziqi ;

Wu, Chuande ;

Yang, Yu ;

Wang, Zhiyu ;

Chen, Banglin ;

Qian, Guodong .

ADVANCED MATERIALS, 2015, 27 (08) :1420-+

[5] A Zn4O-containing doubly interpenetrated porous metal-organic framework for photocatalytic decomposition of methyl orange [J].

Das, Madhab C. ;

Xu, Hui ;

Wang, Zhiyu ;

Srinivas, Gadipelli ;

Zhou, Wei ;

Yue, Yan-Feng ;

Nesterov, Vladimir N. ;

Qian, Guodong ;

Chen, Banglin .

CHEMICAL COMMUNICATIONS, 2011, 47 (42) :11715-11717

[6] Metal-Organic Framework (MOF) Compounds: Photocatalysts for Redox Reactions and Solar Fuel Production [J].

Dhakshinamoorthy, Amarajothi ;

Asiri, Abdullah M. ;

Garcia, Hermenegildo .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (18) :5414-5445

[7] Manufacture of dense coatings of Cu3(BTC)2 (HKUST-1) on α-alumina [J].

Gascon, Jorge ;

Aguado, Sonia ;

Kapteijn, Freek .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 113 (1-3) :132-138

[8] In-situ synthesis of SiO2@MOF composites for high-efficiency removal of aniline from aqueous solution [J].

Han, Tongtong ;

Li, Caifeng ;

Guo, Xiangyu ;

Huang, Hongliang ;

Liu, Dahuan ;

Zhong, Chongli .

APPLIED SURFACE SCIENCE, 2016, 390 :506-512

[9] One-dimensional channel-structured Eu-MOF for sensing small organic molecules and Cu2+ ion [J].

Hao, Zhaomin ;

Song, Xuezhi ;

Zhu, Min ;

Meng, Xing ;

Zhao, Shuna ;

Su, Shengqun ;

Yang, Weiting ;

Song, Shuyan ;

Zhang, Hongjie .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (36) :11043-11050

[10] Cu2O as a photocatalyst for overall water splitting under visible light irradiation [J].

Hara, M ;

Kondo, T ;

Komoda, M ;

Ikeda, S ;

Shinohara, K ;

Tanaka, A ;

Kondo, JN ;

Domen, K .

CHEMICAL COMMUNICATIONS, 1998, (03) :357-358

← 1 2 3 4 5 →