In situ polymerization of starch with lactic acid in aqueous solution and the microstructure characterization

被引：72

作者：

Gong, Qingxia ^{[1
]}

Wang, Li-Qun ^{[1
]}

Tu, Kehua ^{[1
]}

机构：

[1] Zhejiang Univ, Inst Polymer Sci, Hangzhou 310027, Peoples R China

来源：

CARBOHYDRATE POLYMERS | 2006年 / 64卷 / 04期

关键词：

starch; poly(lactic acid); relative reactivity; degree of substitution; degree of polymerization; C-13 magnetic resonance;

D O I：

10.1016/j.carbpol.2005.09.005

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Copolymers of starch grafted with poly (lactic acid) were directly prepared by in situ reaction of cornstarch with lactic acid in aqueous media in the presence of stannous 2-ethyl hexanoate [Sn(Oct)(2)]. The procedure of the graft reaction was elucidated, based on the HPLC analysis, as the ring-opening polymerization (ROP) from starch surface of the small amounts of lactide produced in situ in the reaction system. The detailed chemical microstructure of the resultant graft copolymer was clarified by one- and two-dimensional NMR spectroscopy. Analysis of C-13 NMR spectra of the carbons in starch ring as well as the carbonyl carbons in LA moiety demonstrates that the reactivity of hydroxyl groups at glucopyranan unit of starch decreases in the order of C-6 > C-3 > C-2. The average length of PLA grafts at individual starch ring carbons was also investigated. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：501 / 509

页数：9

共 33 条

[1]

Aburto J, 1999, STARCH-STARKE, V51, P132, DOI 10.1002/(SICI)1521-379X(199904)51:4<132::AID-STAR132>3.0.CO

[2]

2-Z

[3] RELATIVE REACTIVITIES OF AMYLOSE HYDROXYL-GROUPS IN THE REACTION WITH DIKETENE [J].

ARRANZ, F ;

SANCHEZCHAVES, M ;

RIOFRIO, A .

POLYMER, 1987, 28 (11) :1829-1832

[4] Functionalization of amylose with chloroacetate groups and their derivation with alpha-naphthylacetic acid. Heterogeneous hydrolytic behaviour of the resulting adducts [J].

Arranz, F ;

SanchezChaves, M .

REACTIVE & FUNCTIONAL POLYMERS, 1995, 28 (01) :69-74

[5] Graft copolymerization onto starch. II. Grafting of acrylic acid and preparation of it's hydrogels [J].

Athawale, VD ;

Lele, V .

CARBOHYDRATE POLYMERS, 1998, 35 (1-2) :21-27

[6] Preparation of starch-g-polystyrene copolymer by emulsion polymerization [J].

Cho, CG ;

Lee, K .

CARBOHYDRATE POLYMERS, 2002, 48 (02) :125-130

[7] Synthesis and characterization of starch-g-polycaprolactone copolymer [J].

Choi, EJ ;

Kim, CH ;

Park, JK .

MACROMOLECULES, 1999, 32 (22) :7402-7408

[8] HIGH-FIELD, C-13-NMR SPECTROSCOPY OF BETA-D-GLUCANS, AMYLOPECTIN, AND GLYCOGEN [J].

DAIS, P ;

PERLIN, AS .

CARBOHYDRATE RESEARCH, 1982, 100 (MAR) :103-116

[9] Starch derivatives of high degree of functionalization.: Part 2.: Determination of the functionalization pattern of p-toluenesulfonyl starch by peracylation and NMR spectroscopy [J].

Dicke, R ;

Rahn, K ;

Haack, V ;

Heinze, T .

CARBOHYDRATE POLYMERS, 2001, 45 (01) :43-51

[10] Acylation of pullulan by ring-opening of lactones [J].

Donabedian, DH ;

McCarthy, SP .

MACROMOLECULES, 1998, 31 (04) :1032-1039

← 1 2 3 4 →