Metallosupramolecular grid complexes: towards nanostructured materials with high-tech applications

被引：115
作者：
Hardy, John G. [1 ,2 ,3 ]
机构：
[1] Univ Strasbourg, ISIS, F-67000 Strasbourg, France
[2] Univ Texas Austin, Dept Biomed Engn, Austin, TX 78712 USA
[3] J Crayton Pruitt Family Dept Biomed Engn, Gainesville, FL 32611 USA
来源：
CHEMICAL SOCIETY REVIEWS | 2013年 / 42卷 / 19期
关键词：
BUILDING-BLOCKS; COORDINATION CHEMISTRY; METAL-COMPLEXES; SPIN-CROSSOVER; MOLECULAR RECOGNITION; ANTICANCER ACTIVITY; SELF-ORGANIZATION; CRYSTAL-STRUCTURE; INORGANIC ARRAYS; REDOX BEHAVIOR;
D O I：
10.1039/c3cs60061k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metallosupramolecular grid complexes (hereafter referred to as metallogrids) are well-defined oligonuclear metal ion complexes involving essentially planar arrays of the metal ions sited at the points of intersection of square or rectangular metallogrids and possess a variety of interesting optical, electronic, magnetic and supramolecular properties. Herein I aim to give the reader an overview of the synthesis, properties and potential for a variety of high-tech applications of metallogrids.
引用
收藏
页码：7881 / 7899
页数：19
相关论文
共 194 条
[61]  
Harrowfield J., UNPUB
[62]   Biological coordination chemistry, a confluence of chemistry and biochemistry [J].
Harrowfield, JM .
COMPTES RENDUS CHIMIE, 2005, 8 (02) :199-210
[63]   Control of molecular architecture by use of the appropriate ligand isomer: a mononuclear "corner-type" versus a tetranuclear [2 X 2] grid-type cobalt(III) complex [J].
Hausmann, J ;
Brooker, S .
CHEMICAL COMMUNICATIONS, 2004, (13) :1530-1531
[64]  
Holmes S. M., 2007, ABSTR PAP AM CHEM S, V234
[65]   Metals and the Integrity of a Biological Coating: The Cuticle of Mussel Byssus [J].
Holten-Andersen, Niels ;
Mates, Thomas E. ;
Toprak, Muhammet S. ;
Stucky, Galen D. ;
Zok, Frank W. ;
Waite, J. Herbert .
LANGMUIR, 2009, 25 (06) :3323-3326
[66]   L-lactide polymerization utilizing a hydroxy-functionalized 3,6-bis(2-pyridyl)pyridazine as supramolecular (Co)initiator: Construction of polymeric [2x2] grids [J].
Hoogenboom, R ;
Wouters, D ;
Schubert, US .
MACROMOLECULES, 2003, 36 (13) :4743-4749
[67]   Synthesis of star-shaped poly(ε-caprolactone) via 'click' chemistry and 'supramolecular click' chemistry [J].
Hoogenboom, Richard ;
Moore, Brian C. ;
Schubert, Ulrich S. .
CHEMICAL COMMUNICATIONS, 2006, (38) :4010-4012
[68]   Supramolecular Star-Shaped Poly(ethylene glycol) Based on a [2 x 2] Grid-Like Metal Complex [J].
Hoogenboom, Richard ;
Moore, Brian C. ;
Schubert, Ulrich S. .
MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 31 (9-10) :840-845
[69]   Metal-Containing and Metallo-Supramolecular Polymers and Materials [J].
Hornig, Stephanie ;
Manners, Ian ;
Newkome, George R. ;
Schubert, Ulrich S. .
MACROMOLECULAR RAPID COMMUNICATIONS, 2010, 31 (9-10) :771-771
[70]   Synthesis, Crystal Structure, Antioxidant Activity, and DNA-Binding Studies of a Novel Ni(II) [2x2] Grid Complex with a Rigid Bistridentate Schiff Base Ligand [J].
Jia, Lei ;
Xu, Jun ;
Xu, Xi-Ming ;
Chen, Long-Hai ;
Jiang, Peng ;
Cheng, Fei-Xiang ;
Lu, Guang-Nong ;
Wang, Qin ;
Wu, Jin-Cai ;
Tang, Ning .
CHEMICAL & PHARMACEUTICAL BULLETIN, 2010, 58 (08) :1077-1080
234567891011