Metallosupramolecular grid complexes: towards nanostructured materials with high-tech applications

被引:115
作者
Hardy, John G. [1 ,2 ,3 ]
机构
[1] Univ Strasbourg, ISIS, F-67000 Strasbourg, France
[2] Univ Texas Austin, Dept Biomed Engn, Austin, TX 78712 USA
[3] J Crayton Pruitt Family Dept Biomed Engn, Gainesville, FL 32611 USA
关键词
BUILDING-BLOCKS; COORDINATION CHEMISTRY; METAL-COMPLEXES; SPIN-CROSSOVER; MOLECULAR RECOGNITION; ANTICANCER ACTIVITY; SELF-ORGANIZATION; CRYSTAL-STRUCTURE; INORGANIC ARRAYS; REDOX BEHAVIOR;
D O I
10.1039/c3cs60061k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Metallosupramolecular grid complexes (hereafter referred to as metallogrids) are well-defined oligonuclear metal ion complexes involving essentially planar arrays of the metal ions sited at the points of intersection of square or rectangular metallogrids and possess a variety of interesting optical, electronic, magnetic and supramolecular properties. Herein I aim to give the reader an overview of the synthesis, properties and potential for a variety of high-tech applications of metallogrids.
引用
收藏
页码:7881 / 7899
页数:19
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