On assessment of the thermodynamic consistency of data on liquid-vapor equilibrium

被引：0

作者：

Marinichev, AN ^{[1
]}

机构：

[1] St Petersburg State Univ, St Petersburg 198904, Russia

来源：

RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2004年 / 77卷 / 06期

关键词：

Varied Nature; Phase Coexistence; Isothermal Data; Thermodynamic Consistency; Vapor Composition;

D O I：

10.1023/B:RJAC.0000044111.83007.77

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A new method for assessment of the thermodynamic consistency of binary isothermal data on the liquid-vapor equilibrium by calculating the Redlich-Kiester integral with account of how the pressure of phase coexistence depends on the vapor composition is suggested. The Maple 8 software is used to compare the values of the integral and other characteristics calculated for systems with varied nature of departures from the Raoult law.

引用

页码：891 / 895

页数：5