One flask preparation of trifluoromethylated amides from ketones and trifluoromethyltrimethylsilane via Ritter reaction with nitriles

被引:0
|
作者
Tongco, EC [1 ]
Prakash, GKS [1 ]
Olah, GA [1 ]
机构
[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089
关键词
Ritter reaction; (trifluoromethyl)trimethylsilane; trifluoromethylated tertiary amides; hydrolysis; acetonitrile;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Trifluoromethylated amides are prepared in a simple one-flask reaction via the Ritter reaction of the corresponding trifluoromethylated silyl ethers, which themselves are readily obtained from the starting ketones and trifluoromethyltrimethylsilane. The yields are good to average.
引用
收藏
页码:1193 / &
页数:4
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