Determination of the absolute configuration of (+)-2,7(14),10-bisabolatrien-1-ol-4-one from Japanese cedar, Cryptomeria japonica

被引：12

作者：

Kim, CS ^{[1
]}

Morisawa, J ^{[1
]}

Nishiyama, N ^{[1
]}

Kashiwagi, T ^{[1
]}

Tebayashi, S ^{[1
]}

Horiike, M ^{[1
]}

机构：

[1] Kochi Univ, Fac Agr, Dept Bioresource Sci, Nankoku, Kochi 7838502, Japan

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 2002年 / 66卷 / 09期

关键词：

(1S,6R)-2,7(14),10-bisabolatrien-1-ol-4-one; (+)-2,7(14),10-bisabolatrien-1-ol-4-one; cryptomerione; Cryptomeria japonica;

D O I：

10.1271/bbb.66.1997

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The absolute configuration of (+)-2,7(14),10-bisabolatrien-1-ol-4-one, a peculiar sesquiterpenol in the Japanese cedar, Cryptomeria japonica, was determined as (1S,6R)-2,7(14),10-bisabolatrien-1-ol-4-one by comparing the specific rotation values of cryptomeriones respectively converted from (+)-2,7(14),10-bisabolatrienl-ol-4-one and synthesized from (R)-(-)-carvone.

引用

页码：1997 / 2000

页数：4

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