Synthesis, X-ray Structures, and spectroscopic characterization of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni (CH3CH2CH2OC(S)S)2(C5H5N)2]

被引：1

作者：

Juncal, Luciana C. ^{[1
]}

Ferrer, Evelina G. ^{[1
]}

Williams, Patricia A. M. ^{[1
]}

Boese, Roland ^{[2
]}

Gustavo Pozzi, C. ^{[1
]}

Della Vedova, Carlos O. ^{[1
]}

Romano, Rosana M. ^{[1
]}

机构：

[1] Univ Nacl La Plata, Fac Ciencias Exactas, Dept Quim, CEQUINOR UNLP CONICET,CCT La Plata,Associated CIC, Blvd 120 E-60 & 64 1465, RA-1900 La Plata, Argentina

[2] Univ Duisburg Essen, Inst Anorgan Chem, Univ Str 5-7, D-45117 Essen, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2022年 / 794卷

关键词：

Ni(II) complex; O-propyldithiocarbonato complex; Crystal Structure; POTASSIUM XANTHATE; CELL-DEATH; ADDUCTS; BIS(ISOPROPYLXANTHATO)NICKEL(II); HISTORY; COPPER;

D O I：

10.1016/j.cplett.2022.139487

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Single crystals of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni (CH3CH2CH2OC(S)S)(2)(C5H5N)(2)], have been prepared and studied using single crystal X-ray diffraction method and IR spectroscopy. The crystal structure of tetracoordinated Ni(II) xanthate complex, bis(O-propyldithiocarbonato)nickel(II), [Ni(CH3CH2CH2OC(S)S)(2)], was also determined and compared with the pre-viously reported structure. The existence of a cis form for a hexacoordinated species of the [NiS4N2] type is infrequent for this family of complexes.

引用

页数：7

共 48 条

[1] Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide [J].