Convenient Palladium-Catalyzed Reductive Carbonylation of Aryl Bromides Under Gas-Free Conditions

被引:11
作者
Ying, Jun [1 ]
Fu, Lu-Yang [1 ]
Zhou, Chao [1 ]
Qi, Xinxin [1 ]
Peng, Jin-Bao [1 ]
Wu, Xiao-Feng [1 ,2 ]
机构
[1] Zhejiang Sci Tech Univ, Dept Chem, Xiasha Campus, Hangzhou 310018, Zhejiang, Peoples R China
[2] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
基金
中国国家自然科学基金;
关键词
Aryl bromides; Reductive carbonylation; Aldehydes; Palladium catalysis; Synthetic methods; CARBON-MONOXIDE; ORGANIC HALIDES; FORMYLATION; ALDEHYDES; EFFICIENT; IODIDES; CONVERSION; ACID;
D O I
10.1002/ejoc.201800471
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A convenient and efficient palladium-catalyzed reductive carbonylation of aryl and heteroaryl bromides has been developed. With formic acid as the CO source and sodium formate or formic acid as the hydrogen donor, various aromatic and heteroaromatic aldehydes were produced in good to excellent yields (53-94%) under gas-free conditions.
引用
收藏
页码:2780 / 2783
页数:4
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