Effect of magnesium addition on inclusions in H13 die steel

被引:21
作者
Wu, Zheng [1 ]
Li, Jing [1 ]
Shi, Cheng-bin [1 ]
Wang, Liang-liang [1 ]
机构
[1] Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
die steel; inclusions; magnesium; deoxidation; thermodynamics; MGO-CENTER-DOT-AL2O3 SPINEL INCLUSIONS; FE-CR ALLOYS; DEOXIDATION EQUILIBRIA; NONMETALLIC INCLUSIONS; ALUMINUM; NI; FATIGUE; POWDER; IRON; MG;
D O I
10.1007/s12613-014-1010-x
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The effect of magnesium addition on the number, morphology, composition, size, and density of inclusions in H13 die steel was studied. The results show that the total oxygen content in the steel can be significantly decreased to 0.0008wt%. Al2O3 and MnS inclusions are changed into nearly spherical MgO center dot Al2O3 spinel and spherical MgO center dot MgS inclusions, respectively. The number of inclusions larger than 1 mu m decreases and the number of inclusions smaller than 1 mu m increases with increasing magnesium content. V(N,C) precipitates around MgO center dot Al2O3 and MgO center dot MgS inclusions during solidification of liquid steel. The densities of MgO center dot Al2O3 spinel inclusions are lower than that of alumina inclusions. With increasing magnesium content in the Mg-containing inclusions, the density of inclusions decreases, leading to the improvement of inclusion removal efficiency.
引用
收藏
页码:1062 / 1067
页数:6
相关论文
共 18 条
[1]   Effect of Magnesium on Inclusion Formation in Ti-Killed Steels and Microstructural Evolution in Welding Induced Coarse-Grained Heat Affected Zone [J].
Chai Feng ;
Yang Cai-fu ;
Su Hang ;
Zhang Yong-quan ;
Xu Zhou .
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL, 2009, 16 (01) :69-74
[2]   Mechanochemical synthesis of magnesium aluminate spinel powder at room temperature [J].
Domanski, D ;
Urretavizcaya, G ;
Castro, FJ ;
Gennari, FC .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2004, 87 (11) :2020-2024
[3]   Activities of the constituents in spinel solid solution and free energies of formation of MgO, MgO •Al2O3 [J].
Fujii, K ;
Nagasaka, T ;
Hino, M .
ISIJ INTERNATIONAL, 2000, 40 (11) :1059-1066
[4]   Aluminum Deoxidation Equilibrium of Molten Fe-Ni Alloy Coexisting with Alumina or Hercynite [J].
Hayashi, Atsutaka ;
Uenish, Takayuki ;
Kandori, Hirotoshi ;
Miki, Takahiro ;
Hino, Mitsutaka .
ISIJ INTERNATIONAL, 2008, 48 (11) :1533-1541
[5]   Thermal fatigue of materials for die-casting tooling [J].
Klobcar, D. ;
Tusek, J. ;
Taliat, B. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2008, 472 (1-2) :198-207
[6]   EBSD analysis of magnesium addition on inclusion formation in SS400 structural steel [J].
Luo, Sin-Jie ;
Su, Yen-Hao Frank ;
Lu, Muh-Jung ;
Kuo, Jui-Chao .
MATERIALS CHARACTERIZATION, 2013, 82 :103-112
[7]   Thermodynamics of aluminum and manganese deoxidation equilibria in Fe-Ni and Fe-Cr alloys [J].
Ohta, H ;
Suito, H .
ISIJ INTERNATIONAL, 2003, 43 (09) :1301-1308
[8]   Calcium and magnesium deoxidation in Fe-Ni and Fe-Cr alloys equilibrated with CaO-Al2O3 and CaO-Al2O3-MgO slags [J].
Ohta, H ;
Suito, H .
ISIJ INTERNATIONAL, 2003, 43 (09) :1293-1300
[9]   Control of MgO•Al2O3 Spinel Inclusions in Stainless Steels [J].
Park, Joo Hyun ;
Todoroki, Hidekazu .
ISIJ INTERNATIONAL, 2010, 50 (10) :1333-1346
[10]   Effect of structure and nonmetallic inclusions on the intercrystalline fracture of cast steel [J].
Schastlivtsev, V. M. ;
Tabatchikova, T. I. ;
Yakovleva, I. L. ;
Klyueva, S. Yu. .
PHYSICS OF METALS AND METALLOGRAPHY, 2013, 114 (02) :180-189