Some properties of intermetallic compounds of Sn with noble metals relevant for hydrogen electrocatalysis

被引：12

作者：

Pinto, L. M. C. ^{[1
,2
]}

Juarez, M. F. ^{[2
]}

Angelo, A. C. D. ^{[1
]}

Schmickler, W. ^{[2
]}

机构：

[1] Univ Estadual Paulista, Lab Eletrocatalise, Fac Ciencias, BR-17033360 Bauru, SP, Brazil

[2] Univ Ulm, Inst Theoret Chem, D-89069 Ulm, Germany

来源：

ELECTROCHIMICA ACTA | 2014年 / 116卷

关键词：

Carbon monoxide; Hydrogen catalysis; Intermetallic compounds; CARBON-MONOXIDE; CO OXIDATION; ELECTROOXIDATION; ELECTRODES; PLATINUM; METHANOL; PHASES; CATALYSTS; SURFACES; PT3SN;

D O I：

10.1016/j.electacta.2013.11.003

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Using density functional theory and a model developed in our own group, we have investigated the suitability of three intermetallic compounds - AuSn, PdSn, and PtSn - as electrode materials for hydrogen oxidation in fuel cells, focusing on their CO tolerance and their catalytic properties. All three metals were found to have lower susceptibility to be poisoned by CO compared to platinum, but only PtSn promises to be a good catalyst for hydrogen oxidation. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：39 / 43

页数：5

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