Homoleptic octahedral coordination of CH3CN to Mg2+ in the Mg[N(SO2CF3)2]2-CH3CN system

被引：9

作者：

Veryasov, Gleb ^{[1
]}

Matsumoto, Kazuhiko ^{[1
]}

Hagiwara, Rika ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Energy Sci, Dept Fundamental Energy Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 07期

基金：

日本学术振兴会;

关键词：

BIS(TRIFLUOROMETHANESULFONYL) IMIDE ANION; IONIC LIQUID; MAGNESIUM; ELECTROLYTE; COMPLEXES; IDENTIFICATION; (CF3SO2)(2)NH; STABILITY; BATTERIES; CRYSTAL;

D O I：

10.1039/c5dt04821d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-ray diffraction and Raman spectroscopic measurements revealed a homoleptic octahedral coordination of CH3CN to Mg2+ in the [Mg(CH3CN)(6)][TFSA](2) (TFSA = bis(trifluoromethylsulfonyl)imide) crystal structure and in Mg[TFSA](2)/CH3CN electrolytes.

引用

页码：2810 / 2813

页数：4

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