Palladium-Catalyzed Carbonylative Synthesis of 3-Methyleneisoindolin-1-ones from Ketimines with Hexacarbonylmolybdenum(0) as the Carbon Monoxide Source

被引：31

作者：

Wang, Zechao ^{[1
]}

Zhu, Fengxiang ^{[1
]}

Li, Yahui ^{[1
]}

Wu, Xiao-Feng ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

CHEMCATCHEM | 2017年 / 9卷 / 01期

关键词：

C-H BOND; STEREOSELECTIVE-SYNTHESIS; SUBSTITUTED; 3-METHYLENEISOINDOLIN-1-ONES; DERIVATIVES; CYCLIZATION; ACTIVATION; ALKALOIDS; ALKYNES; FUNCTIONALIZATION; ISOINDOLINONE;

D O I：

10.1002/cctc.201601306

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An interesting procedure for the palladium-catalyzed carbonylative synthesis of 3-methyleneisoindolin-1-ones from ketimines was established. By using Mo(CO) 6 (0.3 equiv.) as the solid CO source and through C(sp(2))@H bond activation, the desired 3-methyleneisoindolin-1-ones were isolated in moderate to good yields.

引用

页码：94 / 98

页数：5

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