Recent Progress of Sn-Based Derivative Catalysts for Electrochemical Reduction of CO2

被引：65

作者：

Cheng, Feng ^{[1
,2
]}

Zhang, Xinxin ^{[2
,3
]}

Mu, Kaiwen ^{[2
,3
]}

Ma, Xin ^{[2
]}

Jiao, Mingyang ^{[2
]}

Wang, Zhiheng ^{[2
,3
]}

Limpachanangkul, Paphada ^{[4
]}

Chalermsinsuwan, Benjapon ^{[4
]}

Gao, Ying ^{[1
]}

Li, Yunhui ^{[1
]}

Chen, Zhipeng ^{[2
]}

Liu, Licheng ^{[2
,5
,6
]}

机构：

[1] Changchun Univ Sci & Technol, Sch Chem & Environm Engn, Changchun 130022, Jilin, Peoples R China

[2] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266000, Shandong, Peoples R China

[3] Univ Chinese Acad Sci, Sch Chem Engn, Beijing 100049, Peoples R China

[4] Chulalongkorn Univ, Fac Sci, Dept Chem Technol, 254 Phayathai Rd, Bangkok 10330, Thailand

[5] Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China

[6] Zhejiang Univ, Minist Educ, Key Lab Biomass Chem Engn, Hangzhou 310027, Peoples R China

来源：

ENERGY TECHNOLOGY | 2021年 / 9卷 / 01期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide; electrocatalysis; electrochemical reduction; Sn-based catalysts; MESOPOROUS TIN OXIDE; CARBON-DIOXIDE; ELECTROCATALYTIC REDUCTION; EFFICIENT ELECTROREDUCTION; FORMIC-ACID; ENHANCED ACTIVITY; GRAIN-BOUNDARIES; HIGH-SENSITIVITY; FORMATE; NANOSHEETS;

D O I：

10.1002/ente.202000799

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Using renewable electric power to drive CO2 electrochemical reduction to high-value-added chemical fuels can not only solve the problem of excessive emission of CO2, but also achieve the direct conversion of intermittent electrical energy to chemical energy, which is of great significance for controlling the carbon balance and optimizing the energy consumption structure. In recent years, various kinds of electrocatalysts have been used in the research of the CO2 electrochemical reduction reaction (CO2RR) and some progress has been made in key scientific issues such as improving selectivity and reducing the overpotential of reactions. Due to the low cost, environmental friendliness, and high selectivity to formic acid, Sn-based catalysts are most likely to be applied in the CO2RR field on a large scale. Herein, the research progress of Sn-based catalysts, including the research status of metallic tin catalysts, Sn-based oxides, oxide-derived tin catalysts, Sn-based sulfides, and the four strategies commonly used to improve efficiency and selectivity are systematically summarized and discussed. In addition, the major challenges and several perspectives on the further research directions of Sn-based catalysts for CO2RR are proposed.

引用

页数：18

共 120 条

[1] Bi-Doped SnO Nanosheets Supported on Cu Foam for Electrochemical Reduction of CO2 to HCOOH [J].