Investigation of porous structure polymeric materials based on 1-vinyl-2-pyrrolidone

被引：0
|
作者：
Maciejewska, Malgorzata [1 ]
Zaleski, Radoslaw [2 ]
Gorgol, Marek [2 ]
机构：
[1] Marie Curie Sklodowska Univ, Dept Polymer Chem, Fac Chem, Gliniana 33, PL-20614 Lublin, Poland
[2] Marie Curie Sklodowska Univ, Inst Phys, Dept Nucl Methods, Pl M Curie Sklodowskej 1, PL-20031 Lublin, Poland
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 2018年 / 29卷 / 07期
关键词：
1-vinyl-2-pyrrolidone; PALS; polymer synthesis; porous structure; SURFACE-AREA; POSITRONIUM LIFETIME; COPOLYMERS; MICROSPHERES; SORPTION;
D O I：
10.1002/pat.4312
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Highly cross-linked porous copolymers of 1-vinyl-2-pyrrolidone with divinylbenzene were obtained in the form of microspheres by the free-radical cross-linking copolymerization. The porous structure of the copolymers was created by the use of adequate diluents and stabilizers. The main parameters of the porous structure were determined by nitrogen adsorption/desorption method and positronium annihilation lifetime spectroscopy. It was shown that the determined parameters strongly depend on the chosen approach.
引用
收藏
页码：2042 / 2049
页数：8
相关论文
共 50 条
  • [41] Sorption on porous copolymers of 1-vinyl-2-pyrrolidone-divinylbenzene
    M. Maciejewska
    J. Osypiuk-Tomasik
    Journal of Thermal Analysis and Calorimetry, 2013, 114 : 749 - 755
  • [42] NEW ALTERNATING COPOLYMERS PREPARED FROM 1-PROPENE-1-YLIDENE DICYANATE WITH STYRENE AND 1-VINYL-2-PYRROLIDONE
    MONTHEARD, JP
    BOINON, B
    RODRIGUEZ, F
    PHAM, QT
    WATON, H
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1991, 192 (02): : 341 - 349
  • [43] Characterization of polymeric biocomposite based an poly(vinyl alcohol) and poly(vinyl pyrrolidone)
    Sedlarík, V
    Saha, N
    Kuritka, I
    Sáha, P
    POLYMER COMPOSITES, 2006, 27 (02) : 147 - 152
  • [44] NON-CLASSICAL FREE-RADICAL POLYMERIZATION .5. THE PURIFICATION AND POLYMERIZATION OF 1-VINYL-2-PYRROLIDONE
    BAMFORD, CH
    SCHOFIELD, E
    MICHAEL, DJ
    POLYMER, 1985, 26 (06) : 945 - 950
  • [45] Influence of 1-vinyl-2-pyrrolidone on the morphology and performance of holographic transmission grating formed in polymer-dispersed liquid
    Ma, Ji
    Liu, YongGang
    Ruan, Shengping
    Xuan, Li
    ASID'04: Proceedings of the 8th Asian Symposium on Information Display, 2004, : 623 - 625
  • [46] H-COMPLEX FORMATION AND INFLUENCE ON THE RADICAL COPOLYMERIZATION OF ACRYLIC-ACID AND 1-VINYL-2-PYRROLIDONE IN TETRAHYDROFURAN
    GEORGIEV, GS
    KOSEVA, NS
    CHRISTOV, LK
    POLYMER INTERNATIONAL, 1995, 37 (04) : 277 - 285
  • [47] FORMATION AND RELATIVE REACTIVITY OF COMONOMER H-COMPLEXES IN THE RADICAL COPOLYMERIZATION OF ACRYLIC-ACID WITH 1-VINYL-2-PYRROLIDONE
    GEORGIEV, GS
    KOSEVA, NS
    CHRISTOV, LK
    POLYMER INTERNATIONAL, 1995, 36 (03) : 227 - 237
  • [48] Mass spectrometric characterization of a new 2-hydroxypropyl-β-cyclodextrin derivative bearing methacrylic moieties and its copolymerization with 1-vinyl-2-pyrrolidone
    Janus, L
    Carbonnier, B
    Morcellet, M
    Ricart, G
    Crini, G
    Deratani, A
    MACROMOLECULAR BIOSCIENCE, 2003, 3 (3-4) : 198 - 209
  • [49] Isotope-dilution method for the determination of 1-vinyl-2-pyrrolidone-mercapturic acid as a potential human biomarker for 1-vinyl-2-pyrrolidone via online SPE ESI-LC/MS/MS in negative ionization mode
    Bertram, J.
    Schettgen, T.
    Kraus, T.
    JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2016, 1033 : 321 - 327
  • [50] INTERPOLYMER COMPLEX-FORMATION OF POLYSACCHARIDES WITH POLY(ETHYLENE OXIDE) OR POLY(1-VINYL-2-PYRROLIDONE) THROUGH HYDROGEN-BOND
    OHNO, H
    TAKINISHI, H
    TSUCHIDA, E
    MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS, 1981, 2 (08): : 511 - 515
12345