Investigation of porous structure polymeric materials based on 1-vinyl-2-pyrrolidone

被引:0
|
作者
Maciejewska, Malgorzata [1 ]
Zaleski, Radoslaw [2 ]
Gorgol, Marek [2 ]
机构
[1] Marie Curie Sklodowska Univ, Dept Polymer Chem, Fac Chem, Gliniana 33, PL-20614 Lublin, Poland
[2] Marie Curie Sklodowska Univ, Inst Phys, Dept Nucl Methods, Pl M Curie Sklodowskej 1, PL-20031 Lublin, Poland
关键词
1-vinyl-2-pyrrolidone; PALS; polymer synthesis; porous structure; SURFACE-AREA; POSITRONIUM LIFETIME; COPOLYMERS; MICROSPHERES; SORPTION;
D O I
10.1002/pat.4312
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Highly cross-linked porous copolymers of 1-vinyl-2-pyrrolidone with divinylbenzene were obtained in the form of microspheres by the free-radical cross-linking copolymerization. The porous structure of the copolymers was created by the use of adequate diluents and stabilizers. The main parameters of the porous structure were determined by nitrogen adsorption/desorption method and positronium annihilation lifetime spectroscopy. It was shown that the determined parameters strongly depend on the chosen approach.
引用
收藏
页码:2042 / 2049
页数:8
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