Preparation and visible-light photocatalytic activity of α-Fe2O3/γ-Fe2O3 magnetic heterophase photocatalyst

被引:45
作者
Wei, Zhiwei [1 ]
Wei, Xiucheng [1 ]
Wang, Suiyan [1 ]
He, Deyan [1 ]
机构
[1] Lanzhou Univ, Sch Phys Sci & Technol, Key Lab Magnetism & Magnet Mat, Minist Educ, Lanzhou 730000, Peoples R China
基金
中国国家自然科学基金;
关键词
alpha-Fe2O3/gamma-Fe2O3; Heterophase junction; Nanocomposites; Magnetic materials; Photocatalysis; Visible light; FABRICATION; HETEROJUNCTION; PERFORMANCE; OXIDES; FILM;
D O I
10.1016/j.matlet.2013.12.051
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Magnetic heterophase photocatalyst of alpha-Fe2O3/gamma-Fe2O3 nanorods was prepared by a facile thermal decomposition and redox method. The nanorods were about 100 nm in length and 20 nm in diameter, and well-structured heterophase junctions were formed between alpha-Fe2O3 and gamma-Fe2O3. Visible-light induced photodegradation of model dye rhodamine B was investigated by using the as-prepared alpha Fe2O3/gamma-Fe2O3 nanorods. The material exhibits a remarkably enhanced visible-light photocatalytic activity than the single-phase alpha-Fe2O3 or gamma-Fe2O3 owing to its well-structured interfaces and suitable band configuration. The existence of magnetic gamma-Fe2O3 facilitates the practical application of photocatalysts. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:107 / 110
页数:4
相关论文
共 15 条
[1]   Novel photocatalyst: Titania-coated magnetite. Activity and photodissolution [J].
Beydoun, D ;
Amal, R ;
Low, GKC ;
McEvoy, S .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (18) :4387-4396
[2]   Comparison of the semiconductive properties of sputter-deposited iron oxides with the passive film on iron [J].
Buchler, M ;
Schmuki, P ;
Bohni, H ;
Stenberg, T ;
Mantyla, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (02) :378-385
[3]   Influence of Feature Size, Film Thickness, and Silicon Doping on the Performance of Nanostructured Hematite Photoanodes for Solar Water Splitting [J].
Cesar, Ilkay ;
Sivula, Kevin ;
Kay, Andreas ;
Zboril, Radek ;
Graetzel, Michael .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (02) :772-782
[4]   Preparation and characterization of a magnetically separated photocatalyst and its catalytic properties [J].
Gao, Y ;
Chen, BH ;
Li, HL ;
Ma, YX .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 80 (01) :348-355
[5]   Magnetically separable BiFeO3 nanoparticles with a γ-Fe2O3 parasitic phase: controlled fabrication and enhanced visible-light photocatalytic activity [J].
Guo, Renqing ;
Fang, Liang ;
Dong, Wen ;
Zheng, Fengang ;
Shen, Mingrong .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (46) :18645-18652
[6]   Semiconductor PhotocatalysisMechanistic and Synthetic Aspects [J].
Kisch, Horst .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (03) :812-847
[7]   Photocatalytic oxidative desulfurization of dibenzothiophene under simulated sunlight irradiation with mixed-phase Fe2O3 prepared by solution combustion [J].
Li, Fa-tang ;
Liu, Ying ;
Sun, Zhi-min ;
Zhao, Ye ;
Liu, Rui-hong ;
Chen, Lan-ju ;
Zhao, Di-shun .
CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (07) :1455-1462
[8]   Dependence of electron recombination time and light to electricity conversion efficiency on shape of the nanocrystal light sensitizer [J].
Mazumdar, Sayantan ;
Bhattacharyya, Aninda J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (05) :1494-1498
[9]   Recombination in Quantum Dot Sensitized Solar Cells [J].
Mora-Sero, Ivan ;
Gimenez, Sixto ;
Fabregat-Santiago, Francisco ;
Gomez, Roberto ;
Shen, Qing ;
Toyoda, Taro ;
Bisquert, Juan .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1848-1857
[10]   Simple synthesis of flower-like ZnO by a dextran assisted solution route and their photocatalytic degradation property [J].
Qi, Lei ;
Li, Houshen ;
Dong, Lin .
MATERIALS LETTERS, 2013, 107 :354-356