Solvent effects on the crystal structure of silver pentacyanocyclopentadienide: supramolecular isomerism and solvent coordination

被引：14
作者：
Nimax, P. R. [1 ]
Reimann, D. [1 ]
Suenkel, K. [1 ]
机构：
[1] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany
来源：
DALTON TRANSACTIONS | 2018年 / 47卷 / 25期
关键词：
NITROGEN-DONOR LIGANDS; FORCE-FIELD; POLYMORPHISM; COMPLEXES; POLYMERS; ANION; TRICYANOMETHANIDE; THIACYANOCARBONS; TRANSITION; CHEMISTRY;
D O I：
10.1039/c8dt01276h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Several coordination polymers of silver(i)-pentacyanocyclopentadienide (PCC) were studied by X-ray diffraction to examine the effects of different solvents on supramolecular isomerism of the PCC-ligand. While alcohols yield supramolecular isomers of [Ag(PCC)] without coordination of solvent molecules, less polar solvents show coordinate binding. The influence of solvent polarity can be observed by a gradual change in the lattice structure featuring distinct motifs.
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收藏
页码：8476 / 8482
页数：7
相关论文
共 47 条
[1]   AgC(CN)3-based coordination polymers [J].
Abrahams, BF ;
Batten, SR ;
Hoskins, BF ;
Robson, R .
INORGANIC CHEMISTRY, 2003, 42 (08) :2654-2664
[2]   Extension of the Universal Force Field to Metal-Organic Frameworks [J].
Addicoat, Matthew A. ;
Vankova, Nina ;
Akter, Ismot Farjana ;
Heine, Thomas .
JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2014, 10 (02) :880-891
[3]  
[Anonymous], 1998, Acta Crystallogr.
[4]   Structures of [Ag(tcm)], [Ag(tcm)(phz)1/2] and [Ag(tcm)(pyz)] (tcm = tricyanomethanide, C(CN)3-, phz = phenazine, pyz = pyrazine) [J].
Batten, SR ;
Hoskins, BF ;
Robson, R .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (02) :173-175
[5]   Designing dinuclear iron(II) spin crossover complexes. Structure and magnetism of dinitrile-, dicyanamido-, tricyanomethanide-, bipyrimidine- and tetrazine-bridged compounds [J].
Batten, SR ;
Bjernemose, J ;
Jensen, P ;
Leita, BA ;
Murray, KS ;
Moubaraki, B ;
Smitha, JP ;
Toftlund, H .
DALTON TRANSACTIONS, 2004, (20) :3370-3375
[6]  
Bernhardt E, 2000, Z ANORG ALLG CHEM, V626, P560, DOI 10.1002/(SICI)1521-3749(200002)626:2<560::AID-ZAAC560>3.0.CO
[7]  
2-E
[8]   TOPOS3.2:: A new version of the program package for multipurpose crystal-chemical analysis [J].
Blatov, VA ;
Shevchenko, AP ;
Serezhkin, VN .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2000, 33 :1193-1193
[9]   Relationships among solvent softness scales [J].
Chen, T ;
Hefter, G ;
Marcus, Y .
JOURNAL OF SOLUTION CHEMISTRY, 2000, 29 (03) :201-216
[10]  
CHRISTOPHER RE, 1973, INORG CHIM ACTA, V7, P489
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