Copper (II) Oxide Nanoparticles as an Efficient Catalyst in the Azide-AlkyneCycloaddition

被引：17

作者：

Amini, Mojtaba ^{[1
]}

Anbari, Alireza Pourvahabi ^{[1
]}

Ramezani, Sakine ^{[1
]}

Gautam, Sanjeev ^{[2
]}

Chae, Keun Hwa ^{[3
]}

机构：

[1] Univ Maragheh, Dept Chem, Fac Sci, Maragheh, Iran

[2] Panjab Univ, Dr SS Bhatnagar Univ Inst Chem Engn & Technol, Chandigarh 160014, India

[3] Korea Inst Sci & Technol, Adv Anal Ctr, Seoul 136791, South Korea

来源：

CHEMISTRYSELECT | 2016年 / 1卷 / 15期

关键词：

CLICK CHEMISTRY; ALKYNE CYCLOADDITION; CUO NANOPARTICLES; TERMINAL ALKYNES; REUSABLE CATALYST; THIN-FILMS; CU2O; 1,2,3-TRIAZOLES; NANOSTRUCTURES; WATER;

D O I：

10.1002/slct.201600972

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper (II) oxide nanorods and nanospheres were prepared and their structural, morphological, and electronic properties were investigated by X-ray diffraction analysis, X-ray absorption near edge structure, scanning electron microscope and transmission electron microscope. CuO nanoparticles efficiently cata-lyzes azide-alkyne 1,3-dipolar cycloaddition (CuAAC) reaction producing corresponding 1,2,3-triazole derivatives in excellent yields without use of any additives. The advantages of present protocol are mild reaction conditions, reusability of the catalyst, and applicability to a wide range of substrates.

引用

收藏

页码：4607 / 4612

页数：6

相关论文

共 37 条

[1] Cube-octameric silsesquioxane-mediated cargo copper Schiff base for efficient click reaction in aqueous media [J].

Akbari, Ali ;

Arsalani, Nasser ;

Amini, Mojtaba ;

Jabbari, Esmaiel .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2016, 414 :47-54

[2] Cu and CuO nanoparticles immobilized by silica thin films as antibacterial materials and photocatalysts [J].

Akhavan, O. ;

Ghaderi, E. .

SURFACE & COATINGS TECHNOLOGY, 2010, 205 (01) :219-223

[3] Synthesis, structure, and catalytic properties of copper, palladium and cobalt complexes containing an N,O-type bidentate thiazoline ligand [J].

Amini, Mojtaba ;

Bayrami, Arshad ;

Marashi, Mohammad Nazari ;

Arab, Ali ;

Ellern, Arkady ;

Woo, L. Keith .

INORGANICA CHIMICA ACTA, 2016, 443 :22-27

[4]

[Anonymous], 1984, 1 3 DIPOLAR CYCLOADD

[5] The Potential of Supported Cu2O and CuO Nanosystems in Photocatalytic H2 Production [J].

Barreca, Davide ;

Fornasiero, Paolo ;

Gasparotto, Alberto ;

Gombac, Valentina ;

Maccato, Chiara ;

Montini, Tiziano ;

Tondello, Eugenio .

CHEMSUSCHEM, 2009, 2 (03) :230-233

[6] Click Chemistry beyond Metal-Catalyzed Cycloaddition [J].

Becer, C. Remzi ;

Hoogenboom, Richard ;

Schubert, Ulrich S. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (27) :4900-4908

[7] Application of 1,2,3-triazolylidenes as versatile NHC-type ligands: synthesis, properties, and application in catalysis and beyond [J].

Donnelly, Kate F. ;

Petronilho, Ana ;

Albrecht, Martin .

CHEMICAL COMMUNICATIONS, 2013, 49 (12) :1145-1159

[8] Preparation and characterization of TiO2-nanotube/Ti plates loaded Cu2O nanoparticles as a novel heterogeneous catalyst for the azide-alkyne cycloaddition [J].

Faraji, Masoud ;

Amini, Mojtaba ;

Anbari, Alireza Pourvahabi .

CATALYSIS COMMUNICATIONS, 2016, 76 :72-75

[9] A NEXAFS investigation of the formation and decomposition of CuO and Cu2O thin films on Cu(100) [J].

Gurevich, AB ;

Bent, BE ;

Teplyakov, AV ;

Chen, JG .

SURFACE SCIENCE, 1999, 442 (01) :L971-L976

[10] Copper-catalyzed azide-alkyne cycloaddition (CuAAC) and beyond: new reactivity of copper(I) acetylides [J].

Hein, Jason E. ;

Fokin, Valery V. .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (04) :1302-1315

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