SiO2-TBD as new heterogeneous catalyst for the Nef conversion of secondary nitroalkanes under neat conditions

被引：15

作者：

Ballini, Roberto

Fiorini, Dennis

Maggi, Raimondo

Oro, Chiara

Palmieri, Alessandro

Sartori, Giovanni

机构：

[1] Univ Camerino, Dipartimento Sci Chim, Green Chem Grp, I-62032 Camerino, MC, Italy

[2] Univ Parma, Dipartimento Chim Organ & Ind, Clean Synthet Methodol Grp, I-43100 Parma, Italy

来源：

SYNLETT | 2006年 / 12期

关键词：

reaction; nitroalkanes; ketones; heterogeneous catalysis; solventless conditions; SiO2-TBD;

D O I：

10.1055/s-2006-947358

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of secondary nitroalkanes with neat silica-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD), at room temperature, allows the direct conversion of the secondary nitro groups to the corresponding keto carbonyls.

引用

页码：1849 / 1850

页数：2

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